ACS Combinatorial Science p. 389 - 399 (2019)
Update date:2022-08-05
Topics: Oxidative Addition Reductive Elimination C-H Activation Insertion
Mishra, Nidhi
Singh, Anoop S.
Agrahari, Anand K.
Singh, Sumit K.
Singh, Mala
Tiwari, Vinod K.
Glycosyl triazoles are conveniently accessible and contain multiple metal-binding units that may assist in metal-mediated catalysis. Azide derivatives of d-glucose have been converted to their respective aryltriazoles and screened as ligands for the synthesis of 2-substituted benz-fused azoles and benzimidazoquinazolinones by Cu-catalyzed intramolecular Ullmann type C-heteroatom coupling. Good to excellent yields for a variety of benz-fused heterocyles were obtained for this readily accessible catalytic system.
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