Journal of the American Chemical Society p. 13097 - 13105 (2002)
Update date:2022-07-30
Topics:
Barnes, David M.
Wittenberger, Steven J.
Zhang, Ji
Ji, Jianguo
Fickes, Michael G.
Fitzgerald, Michael A.
King, Steven A.
Morton, Howard E.
Plagge, Frederick A.
Preskill, Margo
Wagaw, Seble H.
The enantioselective synthesis of endothelin-A antagonist ABT-546 has been accomplished via the discovery and development of a highly selective catalytic asymmetric conjugate addition of ketoesters to nitroolefins. Employing just 4 mol % bis(oxazoline)-Mg
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