Chemistry Letters p. 493 - 494 (1997)
Update date:2022-09-26
Topics:
Sugi, Kiyoaki D.
Nagata, Takushi
Yamada, Tohru
Mukaiyama, Teruaki
The enantioselective borohydride reduction using optically active cobalt(II) complex catalysts was successfully applied to various aryl N-diphenylphosphinyl imines, and the corresponding reduced products were obtained in good yields with high enantiomeric excesses (up to 99% ee). The optically active primary amines were obtained by the successive hydrolysis under mild conditions.
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