Tetrahedron Letters p. 3241 - 3245 (2000)
Update date:2022-08-05
Topics:
Tiecco, Marcello
Testaferri, Lorenzo
Bagnoli, Luana
Marini, Francesca
Temperini, Andrea
Tomassini, Cristina
Santi, Claudio
The synthesis of a new chiral non-racemic sulfur containing diselenide is described. The electrophilic selenium reagent, produced from this diselenide by treatment with bromine and silver triflate, has been used to effect the selenomethoxylation and the selenohydroxylation of alkenes. These addition reactions occurred with good chemical yield and with high diastereoselectivities. (C) 2000 Elsevier Science Ltd.
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