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nanoparticles. In addition, TGA/DSC analysis and PXRD data
evidenced the occurrence of a clean vaporization process with-
out premature side decomposition, and of a clear PXRD pattern
dominated by the loss of the cyanide and pyridyl groups. We
have also described a simple and general procedure for the
cross-coupling of nitrogen, oxygen, and sulfur nucleophiles
with aryl iodides catalyzed by CuO nanoparticles in moderate
to good yields. The work towards the development of mixed
valence coordination polymers containing various nitrogen
donor ligands and their catalytic properties is in progress in
our laboratory.
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Acknowledgements
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J. S. O. Evans, D. A. Keen, L. Peters and M. G. Tucker,
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We gratefully acknowledge financial support from the Depart-
ment of Science and Technology, New Delhi (Grant No. SR/FT/
CS-104/2011). We also thank the Director, USIC, University
of Delhi, Delhi, for providing analytical, spectral and Single Crystal
X-ray Diffraction facilities. We are thankful to Prof. W. S. Sheldrick
and Dr Heike Mayer-Figge for their help in crystallography and
improvement of the paper. Special thanks are due to Professor
P. J. Sadler, University of Warwick, UK, and Professor Qiang Xu,
National Institute of Advanced Industrial Science and Techno-
logy (AIST), Osaka, Japan, for their kind encouragement. The
authors sincerely thank the reviewers for their valuable sugges-
tions and comments.
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