(-CH2); 117.4, 129.8, 130.7, 132.0, 133.8, 136.4 (aromatic and olefinic C).
Allyl (p-fluorophenyl)sulfane (Table 6, entry 7): 1H NMR (CDCl3,
d/ppm relative to TMS): 3.47 (2H, d, J = 6.9 Hz, -CH2); 5.01–5.06
(2H, m, =CH2); 5.77–5.91 (1H, m, =CH); 6.96–7.01 (2H, m, 2 ¥ Ar-H);
7.32–7.37 (2H, m, 2 ¥ Ar-H). 13C NMR (CDCl3, d/ppm): 38.6 (-CH2);
115.7, 116.0, 117.7, 133.2, 133.3, 133.6 (aromatic and olefinic C). (p-
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1
Methoxyphenyl)methyl sulfane (Table 4, entry 10): H NMR (CDCl3,
d/ppm relative to TMS): 2.44 (3H, s, -CH3); 3.79 (3H, s, -OMe); 6.85
(2H, d, J = 8.7 Hz, 2 ¥ Ar-H); 7.27 (2H, d, J = 8.7 Hz, 2 ¥ Ar-H). 13
C
NMR (CDCl3, d/ppm): 18.1 (-CH3); 55.4 (-OMe); 114.6 (Ar-C); 128.8
(Ar-C); 130.2 (Ar-C); 158.2 (Ar-C). 1,2-Bis(phenylthio)ethane (Table 4,
entry 18): 1H NMR (CDCl3, d/ppm relative to TMS): 3.08 (4H, s, -CH2);
7.19–7.32 (10H, m, 10 ¥ Ar-H). 13C NMR (CDCl3, d/ppm): 33.3 (-CH2);
126.6 (Ar-C); 129.0 (Ar-C); 129.9 (Ar-C); 134.9 (Ar-C).
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