Journal of the American Chemical Society p. 90 - 96 (1983)
Update date:2022-08-02
Topics:
Katritzky, Alan R.
Kashmiri, M. Akram
Ville, George Z. de
Patel, Ranjan C.
The C-alkylation of 2-nitropropanide by N-substituted pyridiniums is first order in each reactant in Me2SO.The effect on the rate of temperature , N substituent, leaving group, and nucleophile was studied quantitatively.Overall, the evidence excludes an SN2 displacement and suggests that the reactions proceed by a free radical nonchain mechanism.
View MoreLishui Nanming Chemical Co., Ltd
Contact:+86-0578-2134101,2697830
Address:No.19 Tongji Road Shuige Industrial zone
Guangzhou PI & PI Biotech Inc. Ltd.
Contact:+86-20-81716320
Address:Suite 501,198 Kaiyuan Ave.,Science City, Guangzhou,China
Nantong Kaixin Pharma Chemical Co.,Ltd.
Contact:86-513-85250786
Address:2-1103 Huachen Mansion, 111 Gongnong Road,Nantong, Jiangsu, China
Contact:21-7631221 15884421033
Address:326 Science and technology,Shanghai,China
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD
Contact:86-21-60560171
Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Doi:10.1021/jo01294a006
(1980)Doi:10.1016/S0020-1693(00)82550-5
(1983)Doi:10.1021/ja01167a084
(1950)Doi:10.1021/ja01196a056
(1947)Doi:10.1002/chem.201402833
(2014)Doi:10.1021/jo01296a025
(1980)