Organic Letters
Letter
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and NMR and EPR spectroscopy have been conducted and
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photoreaction.
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8414.
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sel, S. J.; Konig, B. ACS Catal. 2016, 6, 8410−
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(7) Shaikh, R.; Ghosh, I.; Konig, B. Chem. - Eur. J. 2017, 23, 12120−
ASSOCIATED CONTENT
* Supporting Information
The Supporting Information is available free of charge on the
12124.
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S
(8) Niu, L.; Liu, J.; Yi, H.; Wang, S.; Liang, X. A.; Singh, A. K.;
Chiang, C. W.; Lei, A. ACS Catal. 2017, 7, 7412−7416.
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Full experimental procedures, spectroscopic character-
izations, computational data, and copies of NMR spectra
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AUTHOR INFORMATION
Corresponding Authors
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(11) (a) Fearnley, A. F.; An, J.; Jackson, M.; Lindovska, P.; Denton,
ORCID
̈
R. M. Chem. Commun. 2016, 52, 4987−4990. (b) Noel Duchesneau,
L.; Lagadic, E.; Morlet-Savary, F.; Lohier, J.−F.; Chataigner, I.;
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Breugst, M.; Lalevee, J.; Gaumont, A.−C.; Lakhdar, S. Org. Lett. 2016,
18, 5900−5903. (c) Garra, P.; Graff, B.; Morlet-Savary, F.; Dietlin, C.;
́
Becht, J.-M.; Fouassier, J.-P.; Lalevee, J. Macromolecules 2018, 51, 57−
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70. For seminal examples on the use of different EDA complexes in
organic synthesis, see: (d) Lima, C. G. S.; Lima, T. D.; Duarte, M.;
Jurberg, I. D.; Paixao, M. W. ACS Catal. 2016, 6, 1389−1407.
(e) Davies, J.; Booth, S. G.; Essafi, S.; Dryfe, R. A. W.; Leonori, D.
Angew. Chem., Int. Ed. 2015, 54, 14017−14021. (f) Zhang, J.; Li, Y.;
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Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
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(12) Fouassier, J. P.; Lalevee, J. Photoinitiators for Polymer Synthesis:
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Scope, Reactivity and Efficiency; Wiley-VCH: Weinheim, 2012; Chapter
9, pp 253−254.
(13) Liu, C.; Szostak, M. Angew. Chem., Int. Ed. 2017, 56, 12718−
12722 and references cited therein.
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We thank the CNRS, Normandie Universite, Labex Synorg
(ANR-11-LABX-0029), the Fonds der Chemischen Industrie,
and the University of Cologne within the Excellence Program
for financial support. We are grateful to the Regional
Computing Center of the University of Cologne for providing
computing time of the DFG-funded High Performance
Computing (HPC) system CHEOPS as well as for their
support.
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(15) Optimizations were performed with B3LYP-D3BJ/6-
31+G(d,p) in the gas phase. Electronic energies were calculated
with B3LYP-D3BJ/aug-cc-pVTZ in CH2Cl2 solution using the iefpcm
model. The aug-cc-pVTZ-PP pseudopotential was used for iodine.
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