J IRAN CHEM SOC
3O4 with other catalysts for the coupling of iodobenzene with phenylboronic acid
Table 9 Comparison results of Pd(0)-ABA-Fe
Entry Catalyst (mol% of Pd)
Condition
Time (min) Yield (%) Ref.
1
2
3
4
5
6
7
Pd NP (1.0 mol%)
H2O, KOH, 100 °C
12 h
120
120
24 h
12 h
24 h
180
95
94
95
88
88
99
97
[45]
[47]
[56]
CA/Pd(0) (0.5–2.0 mol%)
PdCl2 (0.05 mol%)
H2O, K2CO3, 100 °C
DMF, Cs2CO3, 130 °C
EtOH/H2O, K2CO3, 80 °C
THF, Cs2CO3, 80 °C
DMF, Cs2CO3, 100 °C
H2O, K2CO3, 100 °C
Pd/Au NPs (4.0 mol%)
NHC-Pd(II) complex (1.0 mol%)
Pd(II)–NHC complex (1 mol%)
N,N′-bis(2-pyridinecarboxamide)-1,2-benzene palladium
complex (1 mol%)
8
9
PANI-Pd (2.2 mol%)
K2CO3, 1,4-dioxane: H2O (1:1), 95 °C 4 h
H2O, Et3N, r.t. 45
91
98
Pd(0)-ABA-Fe3O4 (0.56 mol%)
This work
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Pd(0)-ABA-Fe3O4 nanoparticles exhibit an excellent cata-
lytic activity, high reusability and air or moisture stability
for the Heck and Suzuki reactions also amination of aryl
halides. This methodology is effective for a wide range of
aryl halide including Cl, Br and I. A high conversion of the
substrates was obtained in C–C coupling reaction using
sodium tetraphenyl borate, phenylboronic acid, styrene,
acrylonitrile and butyl acrylate in the presence of this cata-
lyst. The advantages of this protocol are the use of a com-
mercially available, eco-friendly, cheap, chemically stable
materials, the operational simplicity, practicability and
good to high yields, and more importance the catalyst can
be synthesized readily from inexpensive and commercially
available starting materials. Also, the all reactions were car-
ried out in air atmosphere.
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Acknowledgements This work was supported by the research facili-
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