Journal of the Chemical Society. Chemical communications p. 381 - 383 (1985)
Update date:2022-08-17
Topics:
Okamoto, Tadashi
Sasaki, Ken
Shimada, Mikio
Oka, Shinzaburo
Catalytic cleavage of 1,2-bis(4-methoxyphenyl)ethane-1,2-diol (1a) by chloro(meso-tetraphenylporphyrinato)iron(III) in the presence of N-benzyl-3-carbamoyl-1,4-dihydropyridine under molecular oxygen at room temperature yielded exclusively 4-methoxybenzaldehyde, reproducing most features of the C-C bond cleavage of a vicinal diol catalysed by cytochrome P-450SCC.
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