Tetrahedron p. 2959 - 2968 (1995)
Update date:2022-08-17
Topics:
Christopher Buxton
Fensome, Mark
Heaney, Harry
Mason, Kenneth G.
A study of the decomposition reactions of benzenediazonium-2-carboxylate, carried out in a number of mixed nucleophilic solvents, shows that a number of mechanistic pathways can operate simultaneously and can afford, in addition to products derived from benzyne, products derived from the 2-carboxyphenyl cation and the 2-carboxyphenyl radical: benzyne formation is favoured in halogenated solvents and occurs by the concerted loss of nitrogen and carbon dioxide.
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