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In summary, we have successfully designed and synthesized novel
acenaphthene based D-π-A derivatives with N-substituted donors and
DCMN as an acceptor. All the dyes showed positive solvatochromism
from non-polar (toluene) to polar (DMF) environment. The polarity
plots drawn on the basis of Lippert-Mataga, McRae and Weller model
confer reasonable sign of charge transfer characteristics whereas, the
Rettig model furnishes TICT state for dyes 2a-c which is been used for
the FMR application. Among all the dyes, 2b was found to have the
higher viscosity sensitivity (x = 0.50) as compared to other dyes as well
as traditional FMR (DCVJ, x = 0.41) dye. The DFT calculations re-
ported here deliver
a significantly increased fundamental under-
standing of dyes 2a-c. On the other hand, the polarizability and hy-
perpolarizability values estimated for dyes 2a-c were found be superior
than that of urea which makes the dyes suitable for the non-linear
optical materials.
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Appendix A. Supplementary data
Supplementary material related to this article can be found, in the
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