Photochemical Production and Release of Gaseous NO2
J. Phys. Chem. A, Vol. 109, No. 38, 2005 8525
(21) Zellner, R.; Exner, M.; Herrmann, H. J. Atmos. Chem. 1990, 10,
411.
Conclusions
The dependence of NO2 emission rates on nitrate concentra-
tion and heating rates in the temperature-programmed photolysis
of nitrate-doped polycrystalline ice demonstrates that photoge-
nerated NO2 undergoes extensive chemical and photochemical
losses prior to desorption under typical conditions. The hydro-
lytic disproportionation of photogenerated NO2 into nitrate and
nitrite is the dominant dark loss pathway in ice, even at
subeutectic temperatures.
(22) Warneck, P.; Wurzinger, C. J. Phys. Chem. 1988, 92, 6278.
(23) Zepp, R. G.; Hoigne, J.; Bader, H. EnViron. Sci. Technol. 1987,
21, 443.
(24) Sumner, A. L.; Shepson, P. B. Nature 1999, 398, 230.
(25) Domine, F.; Shepson, P. B. Science 2002, 297, 1506.
(26) Bilski, P.; Chignell, C. F.; Szychlinski, J.; Borkowski, A.; Oleksy,
E.; Reszka, K. J. Am. Chem. Soc. 1992, 114, 549.
(27) Boxe, C. S.; Colussi, A. J.; Hoffmann, M. R.; Tan, D.; Mastro-
marino, J.; Case, A. T.; Sandholm, S. T.; Davis, D. D. J. Phys. Chem. A
2003, 107, 11409.
(28) Dubowski, Y.; Colussi, A. J.; Boxe, C.; Hoffmann, M. R. J. Phys.
Chem. A 2002, 106, 6967.
(29) Dubowski, Y.; Colussi, A. J.; Hoffmann, M. R. J. Phys. Chem. A
2001, 105, 4928.
Acknowledgment. C.S.B. acknowledges support from the
Betty and Gordon Moore Foundation. This work was financed
by NSF grant ATM-0228140.
(30) Thornton, J. A.; Wooldridge, P. J.; Cohen, R. C. Anal. Chem. 2000,
72, 528.
(31) Calvert, J.; Pitts, J. N. Photochemistry; Wiley: New York, 1966.
(32) Schwartz, S. E.; White, W. H. AdV. EnViron. Sci. Eng. 1981, 4, 1.
(33) Seidell, A. Solubilities of Inorganic and Metal Organic Compounds,
3rd ed.; van Nostrand: New York, 1940; Vol. 1.
(34) Schwartz, S. E.; White, W. H. AdV. EnViron. Sci. Technol. 1983,
12, 1.
(35) Rempel, A. W.; Waddington, E. D.; Wettlaufer, J. S.; Worster, M.
G. Nature 2001, 411, 568.
(36) Killawee, J. A.; Fairchild, I. J.; Tison, J. L.; Janssens, L.; Lorrain,
R. Geochim. Cosmochim. Acta 1998, 62, 3637.
(37) Takenaka, N.; Ueda, A.; Daimon, T.; Bandow, H.; Dohmaru, T.;
Maeda, Y. J. Phys. Chem. 1996, 100, 13874.
(38) Dash, J. G.; Fu, H. Y.; Wettlaufer, J. S. Rep. Prog. Phys. 1995,
58, 115.
(39) Gross, G. W.; Gutjahr, A.; Caylor, K. J. Phys. 1987, 48, 527.
(40) Gross, G. W.; Wong, P. M.; Humes, K. J. Chem. Phys. 1977, 67,
5264.
(41) Gross, G. W.; McKee, C.; Wu, C. H. J. Chem. Phys. 1975, 62,
3080.
References and Notes
(1) Platt, U. The Origin of Nitrous and Nitric Acid in the Atmosphere;
Springer-Verlag: New York, 1986; Vol. G6.
(2) Logan, J. A. J. Geophys. Res. 1983, 88, 10785.
(3) Legrand, M.; Mayewski, P. ReV. Geophys. 1997, 35, 219.
(4) Mulvaney, R.; Wagenbach, D.; Wolff, E. W. J. Geophys. Res. 1998,
103, 11021.
(5) Dibb, J. E.; Talbot, R. W.; Munger, J. W.; Jacob, D. J.; Fan, S. M.
J. Geophys. Res. 1998, 103, 3475.
(6) Wolff, E. W. Nitrate in Polar Ice; Springer-Verlag: New York,
1995; Vol. I30.
(7) Beine, H. J.; Domine, F.; Ianniello, A.; Nardino, M.; Allegrini, I.;
Teinila, K.; Hillamo, R. Atmos. Chem. Phys. 2003, 3, 335.
(8) Beine, H. J.; Domine, F.; Simpson, W.; Honrath, R. E.; Sparapani,
R.; Zhou, X. L.; King, M. Atmos. EnViron. 2002, 36, 2707.
(9) Beine, H. J.; Honrath, R. E.; Domine, F.; Simpson, W. R.; Fuentes,
J. D. J. Geophys. Res. 2002, 107.
(10) Dibb, J. E.; Arsenault, M.; Peterson, M. C.; Honrath, R. E. Atmos.
EnViron. 2002, 36, 2501.
(11) Honrath, R. E.; Lu, Y.; Peterson, M. C.; Dibb, J. E.; Arsenault, M.
A.; Cullen, N. J.; Steffen, K. Atmos. EnViron. 2002, 36, 2629.
(12) Davis, D.; Nowak, J. B.; Chen, G.; Buhr, M.; Arimoto, R.; Hogan,
A.; Eisele, F.; Mauldin, L.; Tanner, D.; Shetter, R.; Lefer, B.; McMurry, P.
Geophys. Res. Lett. 2001, 28, 3625.
(42) Gross, G. W. AdV. Chem. Ser. 1968, 27.
(43) Ewing, G. E. J. Phys. Chem. B 2004, 108, 15953.
(44) Menzel, M. I.; Han, S. I.; Stapf, S.; Blumich, B. J. Magn. Reson.
2000, 143, 376.
(45) Cho, H.; Shepson, P. B.; Barrie, L. A.; Cowin, J. P.; Zaveri, R. J.
Phys. Chem. B 2002, 106, 11226.
(46) Henson, B. F.; Robinson, J. M. Phys. ReV. Lett. 2004, 92, 246107.
(47) Hindmarsh, J. P.; Buckley, C.; Russell, A. B.; Chen, X. D.; Gladden,
L. F.; Wilson, D. I.; Johns, M. L. Chem. Eng. Sci. 2004, 59, 2113.
(48) Fukazawa, H.; Sugiyama, K.; Mae, S. J.; Narita, H.; Hondoh, T.
Geophys. Res. Lett. 1998, 25, 2845.
(13) Peterson, M. C.; Honrath, R. E. Geophys. Res. Lett. 2001, 28, 511.
(14) Ridley, B.; Walega, J.; Montzka, D.; Grahek, F.; Atlas, E.; Flocke,
F.; Stroud, V.; Deary, J.; Gallant, A.; Boudries, H.; Bottenheim, J.; Anlauf,
K.; Worthy, D.; Sumner, A. L.; Splawn, B.; Shepson, P. J. Atmos. Chem.
2000, 36, 1.
(15) Jones, A. E.; Weller, R.; Wolff, E. W.; Jacobi, H. W. Geophys.
Res. Lett. 2000, 27, 345.
(16) Honrath, R. E.; Peterson, M. C.; Guo, S.; Dibb, J. E.; Shepson, P.
B.; Campbell, B. Geophys. Res. Lett. 1999, 26, 695.
(17) Chu, L.; Anastasio, C. J. Phys. Chem. A 2003, 107, 9594.
(18) Mack, J.; Bolton, J. R. J. Photochem. Photobiol., A 1999, 128, 1.
(19) Mark, G.; Korth, H. G.; Schuchmann, H. P.; vonSonntag, C. J.
Photochem. Photobiol., A 1996, 101, 89.
(49) Nye, J. F. J. Glaciol. 1989, 35, 17.
(50) Mulvaney, R.; Wolff, E. W.; Oates, K. Nature 1988, 331, 247.
(51) De Angelis, D.; Legrand, M. Ice Core Studies of Global Bio-
geochemical Cycles. NATO ASI Ser., Ser. 1 1995, 30, 361.
(52) Silvente, E.; Legrand, M. Ice Core Studies of Global Biogeochemi-
cal Cycles. NATO ASI Ser., Ser. 1 1995, 30, 225.
(53) Jaffe, D. A.; Zukowski, M. D. Atmos. EnViron. 1993, 27, 2935.
(54) Stottlemyer, R.; Toczydlowski, D. Can. J. Fish. Aquat. Sci. 1990,
47, 290.
(20) Alif, A.; Boule, P. J. Photochem. Photobiol., A 1991, 59, 357.