Journal of Organic Chemistry p. 5160 - 5164 (1983)
Update date:2022-08-29
Topics:
Taylor, Richard T.
Flood, Lawrence A.
A new synthesis of polystyrene-bound phenylselenic acid, from reaction of mercurated polystyrene and selenium dioxide, is described.A triphasic system of the polymer (in catalytic amounts), aqueous hydrogen peroxide, and dichloromethane is shown to be an effective medium for the conversion of olefins into trans diols and ketones into esters.A biphasic system of the polymer and tert-butyl hydroperoxide in refluxing chloroform effects the selective oxidation of benzylic alcohols to the carbonyl species.In a similar catalytic system hydroxy aromatic compounds can be converted into quinones.Conversion of 1,5-dihydroxynaphthalene into juglone can be realized in 70percent yield.
View MoreWeifang Ocean Trading Co., Ltd.
Contact:+86-536-2081155
Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Contact:86-574-26865651
Address:529 YuanBaoShan Road, Beilun District
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
KA-SHING Business Trade Macau Co., Ltd.
Contact:00853-28430045
Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
Nanjing chemipioneer pharmaceutical & technology Co., LTD
website:http://www.chemipioneer.com.cn
Contact:+86-25-52685700
Address:Room 305,A Block,Biological-Medicine Building,Business Start-up Center,Xin-ke 1st Road, High-tech development zone,Nanjing city,Jiangsu Province, China
Doi:10.1021/acs.orglett.7b01882
(2017)Doi:10.1007/s11426-018-9310-y
(2018)Doi:10.1016/j.jcat.2003.12.001
(2004)Doi:10.1002/anie.201909009
(2019)Doi:10.1107/S0108270199014821
(2000)Doi:10.2478/s11532-011-0033-7
(2011)