Tetrahedron p. 953 - 962 (1992)
Update date:2022-08-11
Topics:
Choudary, Boyapati M.
Prasad, Annavajhula Durga
Swapna, Vinukonda
Valli, Velaga L. K.
Bhuma, Vedantam
An efficient method for allylic oxidation of cyclic and acyclic alkenes to the corresponding α,β-unsaturated carbonyl compounds in good yields was described using catalytic amounts of chromiapillared montmorillonite and equimolar quantities of tert-butyl hydroperoxide. This is also a convenient method for selective oxidative deprotection of allyl ethers and amines using same system. Incidentally this is the first heterogeneous system for the allylic oxidation as well as oxidative deprotection.
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