Tetrahedron Letters p. 7945 - 7948 (1995)
Update date:2022-08-10
Topics:
Corey
Palani, Anandan
The selective oxidation of 1,4-diols to γ-lactols by o-iodoxybenzoic acid occurs by a rate-limiting carbonyl-forming elimination pathway in which the carbinol proton is abstracted internally via a six-atom cyclic arrangement, which explains the observed selectivity.
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