Tetrahedron Letters p. 3880 - 3883 (2018)
Update date:2022-08-16
Topics:
Ding, Aishun
Li, Shijie
Chen, Yang
Jin, Ruiwen
Ye, Cong
Hu, Jianhua
Guo, Hao
We report herein a visible light-induced oxidation of triarylphosphines under aerobic condition with excellent functional group tolerance. In this transformation, the photo catalyst 4-phenylthioxanthone acted as a photosensitizer for the in situ generation of singlet oxygen. This new approach provided a cheaper and greener method for the preparation of phosphine oxide, showing great advantages in environmental protocols.
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