10.1002/cctc.201800590
ChemCatChem
FULL PAPER
Crystal data for 7v: C16H15NO; Mr = 237.29, Monoclinic, space group P
21/c, a = 9.3631(5) Å, b = 15.6423 (8) Å, c = 9.6090 (5) Å; V =
1310.01(12) Å 3; T = 293(2) K; Z = 4; Reflections collected/unique,
16973/2667, Rint = 0.0800, R1 = 0.0571, wR2 = 0.1301; GOF = 1.025;
CCDC-1565689 contains the supplementary crystallographic data for this
paper. These data can be obtained free of charge from The Cambridge
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Typical procedure for catalyst recovery and reuse: To a round-
bottom flask was added phenylacetic acid (272 mg, 2.0 mmol),
benzylamine (214 mg, 2.0 mmol), complex 1 (58.8 mg, 0.04 mmol) and
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recovery of catalyst (the recovered catalyst should be dried in a vacuum
oven at 60 oC for 2 hours). For the filtrate, after evaporation of the solvent
a crude amide mixture was obtained. Finally, the product was purified by
column chromatograph on silica gel (petroleum ether/ethyl acetate=1:1).
The same procedure was used for the synthesis of other N-substituted
amides catalyzed by recovered catalyst 1.
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Acknowledgements
The authors thank the National Natural Science Foundation of
China (21536003, 21273068), the Shanxi Province Science
Foundation for Youths (201701D221035), and the PhD Start-up
Foundation of Shanxi Medical University (03201501) for the
financial support.
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Keywords: Lewis acids • N-substituted amides • decamethyl
zirconocene • perfluorooctanesulfonates • homogeneous
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