Tetrahedron p. 2727 - 2736 (1985)
Update date:2022-08-10
Topics:
Montaudon, E.
Rakotomanana, F.
Maillard, B.
The thermolysis of the allyl t-butylperoxide has been performed in esters, acids, anhydrides, nitriles and amides.Only esters and acetonitrile have been 2,3-epoxy propanated.With acids, the reaction product is the alkanoate of the hydroxymethyl-γ-butyrolactone corresponding to the cyclization of the expected epoxyacid and it is isolated with a good yield; the same compound is obtained putting the anhydride in place of the acid.
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