Organometallics
Article
4
0
SADABS based on the Laue symmetry of the reciprocal space, μ =
(c) Dochnahl, M.; Lo
̈
hnwitz, K.; Lu
̈
hl, A.; Pissarek, J.-W.; Biyikal, M.;
−1
3
.62 mm , T = 0.67, Tmax = 0.84. The structure was solved by direct
Roesky, P. W.; Blechert, S. Organometallics 2010, 29, 2637−2645.
min
2
methods and refined against F with a full-matrix least-squares
algorithm using the SHELXTL (version 2008/4) software package;
50 parameters refined. Hydrogen atoms were treated using
appropriate riding models. Goodness of fit, 0.99 for observed
reflections; final residual values, R1(F) = 0.058, wR(F ) = 0.116 for
observed reflections; residual electron density, −2.01 to 2.19 e Å .
(d) Jenter, J.; Luhl, A.; Roesky, P. W.; Blechert, S. J. Organomet. Chem.
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2011, 696, 406−418.
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ASSOCIATED CONTENT
(10) Reviews: (a) Brunet, J.-J.; Chu, N.-C.; Rodriguez-Zubiri, M.
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Eur. J. Inorg. Chem. 2007, 4711−4722. (b) Liu, C.; Bender, C. F.; Han,
X.; Widenhoefer, R. A. Chem. Commun. 2007, 3607−3618. (c) Furster,
̈
*
S
Supporting Information
Files CCDC 848068 (3), 848069 (4), and 797319 (10) contain
the supplementary crystallographic data for this paper. These
request/cif. Experimental details and spectral characterization
A.; Davies, P. W. Angew. Chem. 2007, 119, 3478−3519. (d) Chianese,
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́
4
̈
̈
(
AUTHOR INFORMATION
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*
Mothes, E. Organometallics 2004, 23, 1264−1268. (b) Brunet, J. J.;
Chu, N. C.; Diallo, O. Organometallics 2005, 24, 3104−3110.
(c) Rodriguez-Zubiri, M.; Anguille, S.; Brunet, J.-J. J. Mol. Catal. A
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ACKNOWLEDGMENTS
M. Eur. J. Inorg. Chem. 2007, 4711−4722. (e) Dub, P. A.; Rodriguez-
Zubiri, M.; Daran, J.-C.; Brunet, J.-J.; Poli, R. Organometallics 2009, 28,
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P.C., J.C., R.P., D.S., and M.L. work at CaRLa of Heidelberg
University, being cofinanced by Heidelberg University, the state
of Baden-Wurttemberg, and BASF SE. Support of these
4
(
764−4777.
14) (a) Wang, X.; Widenhoefer, R. A. Organometallics 2004, 23,
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1
2
2
649−1651. (b) Qian, H.; Widenhoefer, R. A. Org. Lett. 2005, 7,
institutions is greatly acknowledged.
635−2638. (c) Bender, C. F.; Widenhoefer, R. A. J. Am. Chem. Soc.
005, 127, 1070−1071. (d) Bender, C. F.; Hudson, W. B.;
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dx.doi.org/10.1021/om200964u | Organometallics 2012, 31, 921−929