Journal of Organic Chemistry p. 150 - 153 (1987)
Update date:2022-08-30
Topics:
Moriarty, Robert M.
Prakash, Om
Duncan, Michael P.
Vaid, Radhe K.
Musallam, Hikmat A.
Hypervalent iodine oxidation of various silyl enol ethers (aromatic, heteroaromatic, aliphatic) using iodosobenzene-boron trifluoride etherate in methanol leads to α-methoxylation of ketones in high yields. The scope and mechanism of the reaction are discussed.
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