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L. Wang et al.
1
1-Dodecylamine. m.p. 28–29◦C (lit.21 28◦C). H NMR (CDCl3): δ
2.65 (t, J = 2.06 Hz, 2H), 2.35 (s, 2H), 1.55-1.30 (m, 20H), 0.89 (t, J =
6.80 Hz, 3H). IR (film): νmax 3458, 3365, 1380 cm−1. (Found: C, 77.85;
H, 14.75; N, 7.40; C12H27N requires: C, 77.76; H, 14.68; N, 7.56).
1
1-Hexadecanamine. m.p. 45–47◦C (lit.22 47◦C). H NMR (CDCl3):
δ 2.68 (t, J = 2.10 Hz, 2H), 2.40 (s, 2H), 1.57-1.29 (m, 28H), 0.90 (t,
J = 6.90 Hz, 3H). IR (KBr): νmax 3462, 3360, 1380 cm−1. (Found: C,
79.82; H, 14.47; N, 5.71; C16H35N requires: C, 79.59; H, 14.61; N, 5.80).
Safety Warning: This procedure involves a high temperature and
pressure and only must be carried out in an apparatus with the appro-
priate pressure rating at the reaction temperature. It also should be
performed in a safe place.
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