Journal of Organometallic Chemistry p. 167 - 182 (1987)
Update date:2022-08-17
Topics:
Castiglioni, Mario
Giordano, Roberto
Sappa, Enrico
The complex (η5-C5H5)NiRu3(μ-H)3(CO)9 catalyses the selective hydrogenation of the therminal double bond of conjugated linear dienes in homogeneous conditions; isomerization of non-conjugated to conjugated dienes and of pent-1-ene to pent-2-ene also occurs.Selective hydrogenation and isomerization of cyclic hexenes and hexadienes takes place without opening of the ring; a reaction scheme is proposed, and the activity of the cluster itself relative to that of its decomposition products is discussed.Its behaviour is compared with the analogous complex (η5-C5H5)NiOs3(μ-H)3(CO)9.
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