Catalysis Science & Technology
Paper
region. The catalytic activity for the 3-hexyn-1-ol hydrogenation
reaction was investigated. AgPd catalysts derived from Ag@SiO2
showed better selectivity to 3-hexen-1-ol than their
monometallic counterparts, which indicates the electronic
interactions of Pd with Ag atoms suppresses the over-
hydrogenation of 3-hexyn-1-ol. The resulting catalysts could be
easily recycled with similar selectivity over multiple cycles.
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Conflicts of interest
There are no conflicts to declare.
Acknowledgements
We would like to acknowledge the National Sciences and
Engineering Research Council of Canada (NSERC) for
financial support. We thank Ning Chen and Yongfeng Hu at
the Canadian Light Source (CLS) for assistance with XAS
measurements. We also thank Dr. Pia Wennek for assistance
with FTIR measurements. EXAFS and in situ XANES
experiments described in this paper were performed at the
Canadian Light Source, which is supported by the Natural
Sciences and Engineering Research Council of Canada, the
National Research Council Canada, the Canadian Institutes of
Health Research, the Province of Saskatchewan, Western
Economic Diversification Canada, and the University of
Saskatchewan.
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