Tetrahedron p. 14689 - 14704 (1998)
Update date:2022-08-17
Topics:
Kita, Yasuyuki
Yoshida, Yutaka
Mihara, Sachiko
Furukawa, Akihiro
Higuchi, Kazuhiro
Fang, Dai-Fei
Fujioka, Hiromichi
An efficient pinacol rearrangement mediated by trialkyl orthoformate has been developed. The reactions of various types of diols with a catalytic amount of a Lewis acid in the presence of an orthoester afforded the rearranged product in good yields via a cyclic orthoester intermediate. This combined system is applicable not only to cyclic and acyclic tri- and tetra- substituted diols but also to the diols having acid-sensitive acetals.
View MoreWuxi Morality Chemical Co., Ltd
Contact:
Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China
Contact:+86-21-56338808
Address:799 Dunhuang Road, Putuo
website:http://www.sincerityenterp.com
Contact:+86-571-88111846
Address:Binjiang Area, Hangzhou
Taizhou Chenyi chemical co. LTD,
Contact:13736652831
Address:NO.273 SHANGHAI SOUTH STREET,LUQIAO DISTRICT,ZHEJIANG PROVINCE,CHINA.
Tai zhou world Pharm & Chem Co., Ltd
Contact:+86-576-85301198
Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Doi:10.1248/cpb.49.287
(2001)Doi:10.1016/S0277-5387(00)84050-4
(1990)Doi:10.1007/BF02494668
(2000)Doi:10.1246/bcsj.55.1912
(1982)Doi:10.1021/j100007a045
(1995)Doi:10.1039/jr9600004562
(1960)