Journal of the American Chemical Society p. 5761 - 5768 (1989)
Update date:2022-07-30
Topics:
Smith, Amos B.
Leenay, Tamara L.
We record here a full account of a highly stereocontrolled, second-generation synthesis of (-)-paspaline (1).The synthesis proceeded via an initial nine-step conversion of (+)-Wieland-Miescher ketone to tricyclic cyclopentanone 5, an intermediate that we
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