DOI: 10.1039/C5GC00249D
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Journal Name
Green Chemistry
ARTICLE
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0 M. S. Yalfani, G. Lolli, A. Wolf, L. Mleczko, T. E. Müller and W.
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Fig. 10 Comparison of diethylformamide (DEF) conversion versus time
on stream over various catalysts. Test temperature: 280 C; 0.6g
catalyst, substrate flow 0.5mL/h.
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1
8 J. Muzart, Tetrahedron, 2009, 65, 8313-8323.
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9 D. A. Bulushev, S. Beloshapkin, and J. R. H. Ross, Catal. Today,
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consideration optimized catalysts (in terms of acidity, crystallite 20 F. Solymosi, Á. Koós, N. Liliom, I. Ugrai, J. Catal. 2011, 279, 213-
size, pore structure) had been suggested and tested for several
2
19.
hundred hour time-on-stream, to validate their industrial
applicability. The high selectivity towards CO and catalyst
stability is achieved by properly tuning the strength of the
catalyst acid centers.
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1 C.J. Rhodes, Sci Prog., 2010, 93, 223-284.
2 E.G. Derouane, J.C. Védrine, R.R. Pinto, P.M. Borges, L. Costa,
M.A.N.D.A. Lemos, F. Lemos and F. R. Ribeiro, Cat. Rev. - Sci.
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Decomposition of formic acid or its derivatives, resulting
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from CO hydrogenation, had been found to be feasible and 23 S. Zheng, H.R. Heydenrych, A. Jentys and J.A. Lercher, J. Phys.
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0
could represent a novel, storable and sustainable source of CO
for the chemical industry in a society not depending solely on
fossil resources.
Chem. B, 2002, 106, 9552-9558.
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4 D. Santi, S. Rabl, V. Calemma, M. Dyballa, M. Hunger and J.
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Acknowledgements
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Authors would like to thanks T. Juraschek, J. M. Potreck 26 F. Lónyi and J. Valyon, Microporous Mesoporous Mater., 2001, 47
,
and S. Wiezorek for their help with catalytic test reactions.
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93–301.
7 E.F. Sousa-Aguiar and Lucia Gorenstin Appel, Catalysis, 2011, 23
84-315. 20 X. Liu, J. Phys. Chem. C, 2008, 112, 5066-5073.
8 X. Liu, J. Phys. Chem. C, 2008, 112, 5066-5073.
This work has been carried out within the project
CO RRECT”. The project (ref. no.01RC1006B) is funded by
the German Federal Ministry of Education and Research
BMBF) within the funding priority “Technologies for
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,
“
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2
(
Sustainability and Climate Protection–Chemicals Processes and 29 J. Penzien, A. Abraham, J.A. van Bokhoven, A. Jentys, T.E. Müller,
CO
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Utilization”.
C. Sievers and J.A. Lercher, J. Phys. Chem. B, 2004, 108, 4116-4126.
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