Tetrahedron Letters p. 7921 - 7924 (1998)
Update date:2022-08-11
Topics:
Komiya, Naruyoshi
Noji, Satoru
Murahashi, Shun-Ichi
Chiral (salen)manganese(III) complex catalyzed oxidation of symmetrical alkanes with iodosylbenzene gives the corresponding optically active ketones (up to 70% ee). The optically active 2-hydroxy-1-indanone (7) thus obtained is a versatile precursor of cis-1-amino-2-indanol (8) which is a key intermediate of chiral auxiliary and anti HIV protease inhibitor (9).
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