Journal of the American Chemical Society p. 4629 - 4633 (1991)
Update date:2022-08-10
Topics:
Lind, Johan
Shen, Xinhua
Eriksen, Trygve E.
Merényi, Gábor
Eberson, Lennart
By means of pulse radiolysis N-bromosuccinimide, SBr, was reduced to its radical anion, SBr?-. Evidence is presented that SBr?- rapidly fragments into the succinimide anion, S-, and a free bromine atom, Br?, which is converted into Br2?- by reacting with Br- present. The rate constant of hydrogen abstraction by Br? from 2-propanol and methanol have been determined. The carbon-centered radical of tert-butyl alcohol was also found to react with SBr yielding Br2?- in the presence of Br-.
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