Journal of the American Chemical Society p. 9800 - 9803 (1995)
Update date:2022-08-30
Topics:
Clennan, Edward L.
Dobrowolski, Piotr
Greer, Alexander
Singlet oxygen reacts with thietane, 1, to give the sulfoxide, 1SO, and a trace of sulfone, 1SO2. A mechanism which involves a novel substrate catalyzed interconversion of a persulfoxide and thiadioxirane intermediate is proposed. The data whic
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