Journal of Materials Chemistry A
Paper
6 X. Meng and F. S. Xiao, Chem. Rev., 2014, 114, 1521–1543.
7 D. K. Pappas, E. Borfecchia, M. Dyballa, I. A. Pankin,
K. A. Lomachenko, A. Martini, M. Signorile, S. Teketel,
B. Arstad, G. Berlier, C. Lamberti, S. Bordiga, U. Olsbye,
K. P. Lillerud, S. Svelle and P. Beato, J. Am. Chem. Soc.,
2017, 139, 14961–14975.
8 R. Oord, J. E. Schmidt and B. M. Weckhuysen, Catal. Sci.
Technol., 2018, 8, 1028–1038.
9 A. Koishybay and D. F. Shantz, J. Am. Chem. Soc., 2020, 142,
11962–11966.
Conclusions
In summary, we have developed a facile embryonic zeolite-
assisted strategy for the highly efficient synthesis of zeolites.
Based on this strategy, SSZ-13 has been successfully synthesized
under ultra-low OSDA usage with a fast crystallization rate, wide
SAR range and high solid yields. It is revealed that the X-ray
amorphous embryonic CHA zeolite has a nanometer size,
large pore volume and abundant D6R units, which contributes
to the fast synthesis of SSZ-13. In addition, SSZ-13 synthesized
from different gel SARs is found to have distinct crystallization
rates, leading to different morphologies and crystal sizes. The
resultant SSZ-1323.2, aer Cu2+ exchange, displays excellent
NH3-SCR activity and high-temperature hydrothermal stability,
which promises its practical application for the NH3-SCR
process. High-silica SSZ-1396.1 is explored as a catalyst for the
MTO reaction, which also presents good catalytic performance.
This facile strategy offers an alternative to other costly and
complicated routes for the synthesis of SSZ-13, and holds
potential for the efficient synthesis of more industrially
important zeolites.
10 A. M. Beale, F. Gao, I. Lezcano-Gonzalez, C. H. Peden and
J. Szanyi, Chem. Soc. Rev., 2015, 44, 7371–7405.
´
11 F. Gao, N. M. Washton, Y. Wang, M. Kollar, J. Szanyi and
C. H. F. Peden, J. Catal., 2015, 331, 25–38.
12 J. Zhang, Y. Shan, L. Zhang, J. Du, H. He, S. Han, C. Lei,
S. Wang, W. Fan, Z. Feng, X. Liu, X. Meng and F.-S. Xiao,
Appl. Catal., B, 2020, 277, 119193–119200.
13 S. Zhang, L. Pang, Z. Chen, S. Ming, Y. Dong, Q. Liu, P. Liu,
W. Cai and T. Li, Appl. Catal., A, 2020, 607, 117855–117876.
14 F. Bleken, M. Bjørgen, L. Palumbo, S. Bordiga, S. Svelle,
K.-P. Lillerud and U. Olsbye, Top. Catal., 2009, 52, 218–228.
15 Q. Zhu, J. N. Kondo, R. Ohnuma, Y. Kubota, M. Yamaguchi
and T. Tatsumi, Microporous Mesoporous Mater., 2008, 112,
153–161.
Author contributions
16 U. Deka, A. Juhin, E. A. Eilertsen, H. Emerich, M. A. Green,
S. T. Korhonen, B. M. Weckhuysen and A. M. Beale, J. Phys.
Chem. C, 2012, 116, 4809–4818.
17 Z. Liu, T. Wakihara, K. Oshima, D. Nishioka, Y. Hotta,
S. P. Elangovan, Y. Yanaba, T. Yoshikawa, W. Chaikittisilp,
T. Matsuo, T. Takewaki and T. Okubo, Angew. Chem., Int.
Ed. Engl., 2015, 54, 5683–5687.
18 Z. Liu, N. Nomura, D. Nishioka, Y. Hotta, T. Matsuo,
K. Oshima, Y. Yanaba, T. Yoshikawa, K. Ohara, S. Kohara,
T. Takewaki, T. Okubo and T. Wakihara, Chem. Commun.,
2015, 51, 12567–12570.
19 I. Yarulina, A. Dikhtiarenko, F. Kapteijn and J. Gascon, Catal.
Sci. Technol., 2017, 7, 300–309.
The manuscript was completed through the contributions of all
authors. All authors have given approval to the nal version of
the manuscript. Linying Wang carried out the experiments and
wrote the dra. Dali Zhu and Juan Wang took part in some of
the synthesis experiments. Wenhao Cui participated in parts of
the characterizations. Jingfeng Han carried out the UV-Raman
test. Bing Li tested the MTO performances. Peng Tian and
Zhongmin Liu guided the research project. Peng Tian and Dong
Fan modied the manuscript.
Conflicts of interest
There are no conicts to declare.
20 J. Han, X. Jin, C. Song, Y. Bi, Q. Liu, C. Liu, N. Ji, X. Lu, D. Ma
and Z. Li, Green Chem., 2020, 22, 219–229.
21 Y. Lv, C. Ye, J. Zhang and C. Guo, Microporous Mesoporous
Mater., 2020, 293, 1–8.
22 Y. Guo, T. Sun, X. Liu, Q. Ke, X. Wei, Y. Gu and S. Wang,
Chem. Eng. J., 2019, 358, 331–339.
23 M. J. Diaz-Cabanas, P. A. Barrett and M. A. Camblor, Chem.
Commun., 1998, 17, 1881–1882.
Acknowledgements
The authors acknowledge the National Natural Science Foun-
dation of China (No. 21991090 and 21991091) and the Key
Research Program of Frontier Sciences, Chinese Academy of
Sciences (Grant No. QYZDB-SSW-JSC040) and DICP Funding
(DICP ZZBS201807).
24 Z. Pourmahdi and H. Maghsoudi, Adsorption, 2017, 23, 799–
807.
25 S. I. Zones, J. Chem. Soc., Faraday Trans., 1990, 86, 3467–
3472.
Notes and references
1 A. Corma, Chem. Rev., 1997, 97, 2373–2419.
2 V. Van Speybroeck, K. Hemelsoet, L. Joos, M. Waroquier, 26 L. Tang, K.-G. Haw, Y. Zhang, Q. Fang, S. Qiu and
R. G. Bell and C. R. A. Catlow, Chem. Soc. Rev., 2015, 44,
7044–7111.
V. Valtchev, Microporous Mesoporous Mater., 2019, 280,
306–314.
3 M. Dusselier and M. E. Davis, Chem. Rev., 2018, 118, 5265– 27 S. I. Zones, J. Chem. Soc., Faraday Trans., 1991, 87, 3709–
5329. 3716.
4 M. E. Davis and R. F. Lobo, Chem. Mater., 1992, 4, 756–768. 28 M. Itakura, I. Goto, A. Takahashi, T. Fujitani, Y. Ide,
5 V. Nikolakis, Curr. Opin. Colloid Interface Sci., 2005, 10, 203–
210.
M. Sadakane and T. Sano, Microporous Mesoporous Mater.,
2011, 144, 91–96.
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