Tetrahedron Letters p. 6957 - 6961 (1999)
Update date:2022-08-30
Topics:
Takaya, Yoshiaki
Ogasawara, Masamichi
Hayashi, Tamio
Rhodium-catalyzed asymmetric 1,4-addition to α,β-unsaturated ketones is effected by use of arylborates, generated in situ by lithiation of aryl bromides followed by treatment with trimethoxyborane, to give the corresponding β-aryl ketones of up to 99% ee
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