Journal of Organometallic Chemistry p. 339 - 348 (1987)
Update date:2022-08-17
Topics:
Iyer, Savithri R.
Tueting, David R.
Schore, Neil E.
The synthesis of the potential bridging ligand (C6H5)2PCH2CH2Si(CH3)2C5H4 (3) is described.The ferrocene (6) derived from 3 has been found to form macrocyclic complexes with metal fragments NiCl2, NiBr2, and Co2(CO)6.Although monomeric, bimetallic products might have been expected based upon the reduced steric demands of ligand 3 relative to an analogous ligand, (C6H5)2PCH2Si(CH3)2C5H4 (1), it appears that the increased flexibility in 3 is the overriding factor leading to a preference for inter- rather than intramolecular coordination of the second phosphine function in 6.
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