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ChemComm
DOI: 10.1039/C7CC02380D
COMMUNICATION
Journal Name
Additionally, with full conversion reached within few hours and a 20.
very low catalyst loading, this approach proved to be a sustainable
F.-X. Felpin and Y. Landais, The Journal of Organic
Chemistry, 2005, 70, 6441-6446.
alternative to classic allylation procedures of bio-based phenols.
Furthermore, this catalytic system enabled the allylation of lignin
with a selectivity for the aromatic hydroxyl groups (up to 82%
conversion). Poisoning experiments and TEM analysis of the
recovered nanoparticles suggest that the mechanism proceeds
mainly heterogeneously at 80 °C.
2
1.
2.
B. C. Ranu, K. Chattopadhyay and L. Adak, Organic
Letters, 2007, 9, 4595-4598.
2
T. Mitsudome, K. Nose, K. Mori, T. Mizugaki, K. Ebitani, K.
Jitsukawa and K. Kaneda, Angewandte Chemie
International Edition, 2007, 46, 3288-3290.
2
3.
4.
J. Liu, G. Hu, Y. Yang, H. Zhang, W. Zuo, W. Liu and B.
Wang, Nanoscale, 2016, 8, 2787-2794.
Keywords: palladium • nanoparticle • catalysis • Tsuji-Trost • lignin
2
J. Liu, X. Huo, T. Li, Z. Yang, P. Xi, Z. Wang and B. Wang,
Chemistry – A European Journal, 2014, 20, 11549-11555.
Y. Uozumi, Pure Appl. Chem., 2007, 79, 1481-1489.
R. Moucel, K. Perrigaud, J.-M. Goupil, P.-J. Madec, S.
Marinel, E. Guibal, A.-C. Gaumont and I. Dez, Advanced
Synthesis & Catalysis, 2010, 352, 433-439.
Acknowledgements
The authors would like to thank S. Essig, K. Nagel, and H. Köhler
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5.
6.
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(IKFT) for technical support and T. Bantle and F. Mack for
experimental support.
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