Angewandte
Communications
Chemie
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In conclusion, we realized atomic dispersion of active sites
in an extended MOF, thus generating photocatalysts with
higher activity in CO2 reduction. Unique structural character-
istics of the developed catalyst include a large surface area
and strong CO2 adsorption ability. As demonstrated by an
energy transfer efficiency investigation, as well as first-
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effectively transferred to the active sites, which not only
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easily captured and subsequently photocatalytically reduced
into CO and CH4 with dramatically improved performance in
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Acknowledgements
This research received financial support from the World
Premier International Research Center Initiative (WPI
Initiative) on Materials Nanoarchitectonics (MANA),
MEXT (Japan), and the National Basic Research Program
of China (973 Program, 2014CB239301 and NSFC11605225).
J.D. acknowledges support from the Jianlin Xie Foundation of
the Institute of High Energy Physics, Chinese Academy of
Sciences.
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Keywords: active sites · CO2 reduction ·
heterogeneous catalysis · photocatalysis ·
solar-energy conversion
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Received: September 2, 2016
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Angew. Chem. Int. Ed. 2016, 55, 1 – 6
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