Inorganic Chemistry
COMMUNICATION
Table 1. Results of the Exploration of the Catalytic Activity of
Compound 1 (Room Temperature, Ar Atmosphere, and Gas
Chromatography Monitoring of the Conversion)
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a
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substrate
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benzaldehyde
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3
25
25
51
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2-naphthaldehyde
9.2
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a
The given data represent the averages of two independent studies.
1827–1836.
(
(
(
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In summary, a new three-dimensional [Fe-Ag] MOF with a
large channel window and 23.8% solvent-accessible space was
synthesized, and its magnetic properties and size-selective Lewis
acid catalysis for cyanosilylation reactions were studied.
perspectives.
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’
ASSOCIATED CONTENT
S. A.; Bominaar, E. L.; Achim, C.; Dunbar, K. R. J. Am. Chem. Soc. 2007,
129, 6104–6116.
S
Supporting Information. CIF of 1, crystal packing dia-
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L.; Grandjean, F.; de Gelder, R.; Mutikainen, I.; Turpeinen, U.; Reedijk,
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b
grams, TGA plot, XRD pattern, synthesis and characterization
details of 1, and details of catalysis experiments. This material is
available free of charge via the Internet at http://pubs.acs.org.
(
30) Tanase, S.; Marques-Gallego, P.; Browne, W. R.; Hage, R.;
Bouwman, E.; Feringa, B. L.; Reedijk, J. Dalton Trans. 2008, 2026–2033.
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(
’
AUTHOR INFORMATION
2
2
1
(
Corresponding Author
*E-mail: dehnen@chemie.uni-marburg.de.
(
(
’
ACKNOWLEDGMENT
Whitcomb, D. R.; Winslow, J.; Zou, C. J. Imaging Sci. Technol. 1996,
40, 417–422.
(35) Spek, A. L. J. Appl. Crystallogr. 2003, 36, 7–13.
This work was financially supported by the Deutsche For-
schungsgemeinschaft. We thank C. Pietzonka for the magnetic
measurements.
(
(
36) Spek, A. L. Acta Crystallogr. 2009, D65, 148–155.
37) We are very grateful to one of the reviewers for drawing our
attention to a correct interpretation of the magnetic properties.
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