ACCEPTED MANUSCRIPT
Table 2. Conversion percentages of some cyclic olefins in
Mukaiyama epoxidation reaction after 3 hours.
Weiner, R. G. Finke, J. Mol. Catal. A: Chem. 1996, 114, 15.
C) B. B Wentzel, P.A. Gosling, M. C. Fieters, R. J. M Nolte,
(
Substrate
Conversion(%)
Epoxide
selectivity(%)
J. Chem. Soc., Dalton Trans, 1998, 13, 2241.
7] W. Nam, H. J. Kim, S. H. Kim, R. Y. N. Ho, and J. S.
Valentine, Inorg. Chem., 1996, 35, 1045.
8] H. R. Khavasi, K. Sasan, M. Pirouzmand, and S. N.
Ebrahimi, Inorg. Chem. 2009, 48, 5593.
9] C-M. Che and W-K. Cheng, J. Chem. Soc., Chem. Commun.,
[
[
[
[
[
[
[
Cyclopentene
-methyl-cyclohexene
Cycloheptene
90%
98%
84%
80%
>99%
>99%
>99%
>99%
1
Cyclooctene
1
986,1443.
10] J.-Y. Qi, Y.M Li, Z. Y Zhou, C. M. Che, C. H. Yeung, A. S.
The condition of reaction is: Substrate (0.88 mmol), catalyst
C. Chan, Adv. Synth. Catal. 2005, 347, 45.
-
3
(
(
1.76×10 mmol), isobutyraldehyde (1.76 mmol), and pure O2
1 atm) in 2 mL of 1,2-dichlroethane as a solvent, in room
11] Z. Li, C. Liu, R. Tang, and G. Liu, RSC. Adv., 2013,
745.
12] J. Y. Qi, L. Q. Qiu, K. H. Lam, C. W. Yip, Z. Y. Zhou, A. S.
C. Chan, Chem. Commun 2003, 1058.
13] (a) A. Willing, H. Follmann, G. Auling, Eur. J. Biochem.,
988, 178, 603. (b) K. Wieghardt, Angew. Chem. Int. Ed.
3,
9
temperature. Gas chromatography determination based on
chlorobenzene as an internal standard. The main byproduct is 2-
cyclohexen-1-one (from GC analysis)
,
1
Notes and references
Department of Chemistry, Sharif University of Technology,
Tehran 11155-3615, Iran, e-mail: bagherzadeh@sharif.edu
Engl., 1989, 28, 1153.
a
[
14] H. R. Khavasi, A. Ghanbarpour, A. A. Tehrani,
CrystEngComm. 2014, 16, 749.
b
[15] (a) T.V. Filippova, E.A. Blyumberg, Russ. Chem. Rev
982, 51, 582. (b) C. L. Hill, Nature, 1999, 401, 436.
,
Faculty of Chemistry, Shahid Beheshti University, G. C.,
1
Evin, Tehran 1983963113, Iran, e-mail: h-khavasi@sbu.ac.ir
Electronic Supplementary Information (ESI) available:
Experimental details for synthesized compounds (CCDC
No. 1008240), full crystallographic data, selected bond
distances and bond angles and hydrogen bonding
parameters.
References
[
1] (a) L. Haughton and J. M. J Williams, J. Chem. Soc., Perkin
Trans. 1, 1999, 2645. b) K. A. Jorgenson, Chem. Rev. 2004,
1
04, 1047.
[
2] (a) M. Amini, M. M. Haghdoost, M Bagherzadeh, Coord.
Chem. Rev., 2014, 268, 83. (b) M. Bagherzadeh, M. M.
Haghdoost, A. Ghanbarpour, M. Amini, H. R. Khavasi, E.
Payab, A. Ellern, L. K. Woo, Inorg. Chim. Acta, 2014, 411
1. (c) M. Amini, M. M. Haghdoost, M Bagherzadeh, Coord.
Chem. Rev., 2013, 257, 1039. (d) M. Bagherzadeh, L.
Tahsini, R. Latifi, Catal. Commun, 2008, , 1600.
3] (a) D. H. R. Barton, A. E Martell, D. T. Sawyer, The
Activation of Dioxygen and Homogeneous Catalytic
,
6
9
[
[
Oxidation; Plenum: New York, 1993. (b) J. Piera, J-E.
Bäckvall, Angew. Chem. Int. Ed., 2008, 47, 3506. (c) T.
Punniyamurthy, S. Vellusamy, and J. Iqbal, Chem. Rev.,
2
005, 105, 2329.
4] (a) T. Yamada and T. Mukaiyama, Chem. Lett., 1989, 18
19. (b) T. Yamada, K. Imagawa, and T. Mukaiyama, Chem.
Lett. 1992, 21, 2109.
,
5
[
[
5] K. R. Rodgers, I. M. Arafa, and H. M. Goff, J. Chem. Soc.,
Chem. Commun., 1990, 19, 1323.
6] (a) B. B. Wentzel, P. L. Alsters, M. C. Feiters, and R. J. M.
Nolte, J. Org. Chem., 2004, 69, 3453. (b) N. Mizuno, H.
4