Tetrahedron Asymmetry p. 535 - 538 (1992)
Update date:2022-08-29
Topics:
Arai, Yoshitsugu
Kontani, Tohru
Koizumi, Toru
An asymmetric synthesis of Elaeocarpus alkaloids, (+)-elaeokanine A and (+)-elaeokanine C is described.The key steps involve an asymmetric Diels-Alder reaction of a chiral sulfinyl dienophile, diastereoselective nucleophilic addition to the acyliminium ion and retro Diels-Alder reactions.
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