Tetrahedron p. 5133 - 5146 (1993)
Update date:2022-08-11
Topics:
Toke, Laszlo
Hell, Zoltan
Szabo, Gabor T.
Toth, Gabor
Bihari, Maria
Rockenbauer, Antal
Single electron transfer induced elemental steps have been shown to occur during the transformation of iodomalonic esters and related CH-acids to cyclopropane derivatives under solid-liquid phase transfer catalytic conditions. The iodo derivatives are formed from iodine and CH-acids "in situ", in the same pot in which the transformations to cyclopropane derivatives take place. A number of electrophilic cyclopropanes with a wide range of substituents have been synthetised by this route.
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