Journal of Fluorine Chemistry p. 283 - 290 (1982)
Update date:2022-08-16
Topics:
Shack, Carl J.
Christe, Karl O.
Iodine monofluorosulfate has been found to react with fluoroolefins in the absence of a solvent to give the corresponding iodo alkyl fluorosulfates by addition of -I and -OSO2F across the double bond.The observed products were ICF2CF2SO3F, CF3CFICF2SO3F, and the isomer mixture ICF2CFClSO3F and ICFClCF2SO3F.Perfluorocyclobutene was unreactive.The iodine fluorosulfate used for this study was synthesized from the reactions of either I2 or RfI with ClSO3F, with both reactions being new routes to this compound.These iodo fluorocarbon fluorosulfates are novel compounds and were characterized by spectroscopy and by formation of the derivatives CF3CFICFO and ICF2CFO.
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