Journal of Organic Chemistry p. 2585 - 2594 (1992)
Update date:2022-08-24
Topics:
Heathcock, Clayton H.
Ruggeri, Roger B.
McClure, Kim F.
Biomimetic total syntheses of (+/-)-daphnilactone A (6) and (+/-)-methyl homodaphniphyllate (4) have been carried out.The syntheses began with the preparation of tricyclic lactone ether 18d, which was reduced to diol 19d with LiAlH4.Oxidation of 19d gave
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