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laser shots were read out at 100 Hz from the CCD, which
was synchronized with the laser system. The reference
spectrum was used for correction of spectral fluctuations
of the probe pulse. The relative polarization of the pump
and probe pulses was set at the magic angle (54.7°). To
calibrate the chirp of the probe pulse, we recorded the
wavelength dependence of OKE (optical Kerr effect) sig-
nals of the solvent. The time-zero dispersion curve was
obtained, and the time origin of the time-resolved absorp-
tion data was corrected accordingly. The effective time
resolution after this time-zero correction was ~150 fs.
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(7) Shin, N.; Hanaoka, K.; Piao, W.; Miyakawa, T.; Fujisawa, T.;
ASSOCIATED CONTENT
Takeuchi, S.; Takahashi, S.; Komatsu, T.; Ueno, T.; Terai, T.;
Tahara, T.; Tanokura, M.; Nagano, T.; Urano, Y. ACS Chem. Biol.,
Supporting Information. Synthesis, experimental details,
femtosecond time-resolved absorption measurements and in
vitro analysis of azoSeR. This material is available free of
charge via the Internet at http://pubs.acs.org.
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3
017, 12, 558-563.
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Stem Cell 2010, 7, 150-161.
AUTHOR INFORMATION
Corresponding Author
(10) Fernández-Lodeiro, J.; Pinatto-Botelho, M. F.; Soares-
Paulino, A. A.; Gonçalves, A. C.; Sousa, B. A.; Princival, C.; Dos
Santos, A. A. Dyes Pigm. 2014, 110, 28-48.
*
*
(11) (a) Davies, K. S.; Linder, M. K.; Kryman, M. W.;, Detty, M. R.
Bioorg. Med. Chem. 2016, 24, 3908-3917. (b) McIver, Z.
A.; Kryman, M. W.; Choi, Y.; Coe, B. N.; Schamerhorn G.
A.; Linder, M. K.; Davies, K. S.; Hill, J. E.; Sawada, G. A.; Grayson,
J. M.; Detty, M. R. Bioorg. Med. Chem. 2016, 24, 3918-3931. (c)
Sabatini, R. P.; Mark, M. F.; Mark, D. J.; Kryman, M. W.; Hill, J.
E.; Brennessel, W. W.; Detty, M. R.; Eisenberg, R.; McCamant, D.
W. Photochem. Photobiol. Sci. 2016, 15, 1417-1432. (d) Kryman, M.
W.; McCormick, T. M.; Detty, M. R. Organometallics, 2016, 35,
ACKNOWLEDGMENT
This work was supported in part by JSPS KAKENHI Grant
Numbers 26104509, 16H00823 and 16H05099 to K.H., JP
25104005 to T.Tahara, JP16H04102 to S.T., JP16K17859 to T.F.,
and SENTAN, JST to K.H., and grants to K.H. from Mochida
Memorial Foundation for Medical and Pharmaceutical
Research. P.W. was supported by a Grant-in-Aid for JSPS
Fellows.
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944–1955.
12) (a) Detty, M. R.; Prasad, P. N.; Donnelly, D. J.; Ohulchanskyy,
T.; Gibson, S. L.; Hilf, R. Bioorg. Med. Chem. 2004, 12, 2537-2544.
b) Ohulchanskyy, T. Y.; Donnelly, D. J.; Detty, M. R.; Prasad, P.
(
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