Carbohydrate Research p. 29 - 42 (1995)
Update date:2022-08-23
Topics:
Herbst, Roswitha
Steiner, Thomas
Pfannemueller, Beate
Saenger, Wolfram
N-(n-octyl)-6-deoxy-D-gluconamide crystallizes in the orthorhombic space group P212121, with a = 5.4524(5), b = 16.662(3), and c = 36.897(5) Angstroem.The structure was determined by X-ray diffraction and refined to R = 9.2percent.The asymmetric crystal unit contains two molecules (A, B) with significantly different conformations.In contrast to the crystal structures of the N-(n-alkyl)-D-gluconamide family, in which the molecules were found arranged in head-to-tail monolayers, molecules A and B form a complex motif with pairwise alternating orientations andinterdigitating antiparallel aliphatic chains.The two symmetry independent molecules form considerably different hydrogen bond patterns.Keywords: Alkyl-gluconamides; Amphiphilic molecules; Aliphatic chain packing; Crystal packing; Hydrogen bonding
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