Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1677 - 1682 (1989)
Update date:2022-08-12
Topics:
Volod'kin, A. A.
Zaitsev, A. S.
Rubailo, V. L.
Belyakov, V. A.
Zaikov, G. E.
A mechanism is proposed for the reaction of 2,6-di-tert-butylphenol with methyl acrylate in the presence of potassium 2,6-di-tert-butylphenoxide and KOH and, based on a computer calculation of the kinetic scheme, the constants have been found for the elementary stages of the reaction, sufficient to interpret the experimental data.The alkylation of 2,6-di-tert-butylphenol by methyl acrylate takes place by an inhibited catalytic chain mechanism involving the participation of ion pairs in the reaction.
View More
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
SHAANXI TOP PHARM CHEMICAL CO.LTD
Contact:+86-029-85733403
Address:No.108 ,west sector,south er huan,xi'an,china
Suzhou Ryan Pharmachem Technology Co.,Ltd
Contact:+86-0512-68780025
Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Shandong Wanda Organosilicon New Material Co., Ltd
Contact:+86-21-54177116;54302881
Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
Beijing Mashi Fine Chemical Co.,Ltd.
Contact:+86-10-61271592
Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Doi:10.1016/j.electacta.2005.03.049
(2005)Doi:10.1016/j.tetlet.2017.02.077
(2017)Doi:10.1039/c7cc05297a
(2017)Doi:10.1039/jr9500002100
(1950)Doi:10.1039/b101434j
(2001)Doi:10.1021/ic101528d
(2010)
