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Basic information

  • Name:

  • Furfuryl alcohol

  • CAS No.:

  • 98-00-0

  • Formula:
  • C5H6O2
  • Synonyms:
  • 2-Furylcarbinol;alpha-Furylcarbinol;2-(Hydroxymethyl)furan;Furylcarbinol (VAN);Furfurylcarb;1/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H;Methanol, (2-furyl)-;2-Furfurylalkohol;5-17-03-00338 (Beilstein Handbook Reference);Furfuryl alcohol [UN2874] [Poison];.alpha.-Furylcarbinol;.alpha.-Furfuryl alcohol;2-Furanylmethanol;2-Furylmethanol;2-Furanmethanol;2-Furfuryl alcohol;Furfuralcohol;Furfurylalkohol;Furan-2-methanol;Furfurol (2-Furfuryl alcohol);Furylcarbinol;NCI-C56224;Furfuranol;2-Furfurylalkohol [Czech];FEMA No. 2491;

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Chemistry

The Molecular Structure of Furfuryl alcohol (CAS NO.98-00-0):


Empirical Formula: C5H6O2
Molecular Weight: 98.0999 
IUPAC Name: furan-2-ylmethanol    
Product Categories: Furans;alcohol Flavor
Appearance: clear yellow liquid
Nominal Mass: 98 Da
Average Mass: 98.0999 Da
Monoisotopic Mass: 98.036779 Da 
Index of Refraction: 1.492
Molar Refractivity: 25 cm3
Molar Volume: 86 cm3
Surface Tension: 38.8 dyne/cm
Density: 1.14 g/cm3
Flash Point: 65 °C
Enthalpy of Vaporization: 42.98 kJ/mol
Boiling Point: 170 °C at 760 mmHg
Vapour Pressure: 1.01 mmHg at 25°C
Melting point: -29 ºC
Refractive index: 1.485-1.487
Water solubility: MISCIBLE 
InChI
InChI=1/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H2
Smiles
Synonyms: c1(ccco1)CO ; AI3-01171 ; BRN 0106291 ; CCRIS 2922 ; NCI-C56224 ; NSC 8843 ; UNII-D582054MUH ; EINECS 202-626-1 ; FEMA No. 2491 ; UN2874 ; HSDB 711  

Uses

 Furfuryl alcohol (CAS NO.98-00-0) has been used in rocketry as a fuel which ignites hypergolically (immediately and energetically in contact) with white fuming nitric acid or red fuming nitric acid oxidizer.The use of hypergolics avoids the need for an igniter. Furfuryl alcohol (CAS NO.98-00-0) is probably a BK channel agonist.and may be used as a food additive.

Production

 Furfuryl alcohol (CAS NO.98-00-0) is manufactured industrially by the catalytic reduction of FURFURAL which is obtained from corncobs and sugar cane bagasse. It finds use as a solvent, but is primarily used as an ingredient in the manufacture of various chemical products such as foundry resins, adhesives, and wetting agents.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 oral 360mg/kg (360mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974.
mouse LCLo inhalation 597ppm/6H (597ppm)   "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
mouse LD50 oral 160mg/kg (160mg/kg)   Biochemical Journal. Vol. 34, Pg. 1196, 1940.
mouse LD50 unreported 338mg/kg (338mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.
rabbit LD50 intravenous 650mg/kg (650mg/kg)   Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 8, Pg. 294, 1949.
rabbit LD50 skin 400mg/kg (400mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
rabbit LD50 unreported 632mg/kg (632mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.
rat LC50 inhalation 233ppm/4H (233ppm)   American Industrial Hygiene Association Journal. Vol. 19, Pg. 91, 1958.
 
rat LD50 intraperitoneal 650mg/kg (650mg/kg)   Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 64, 1974.
rat LD50 oral 177mg/kg (177mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: CYANOSIS		 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(9), Pg. 52, 1981.
rat LD50 skin 3825mg/kg (3825mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(9), Pg. 52, 1981.
rat LD50 subcutaneous 85mg/kg (85mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
rat LD50 unreported 460mg/kg (460mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.

Safety Profile

Hazard Codes: HarmfulXn
Risk Statements: 20/21/22 
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 23-36/37/39 
S23: Do not breathe vapour
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR: UN 2874 6.1/PG 3
WGK Germany: 1
RTECS: LU9100000
F 8: Photosensitive
HazardClass: 6.1
PackingGroup: III

Specification

 Furfuryl alcohol (CAS NO.98-00-0) is also called as 2-Furancarbinol ; 2-Furanmethanol ; 2-Furfuryl alcohol ; 2-Furfurylalkohol [Czech] ; 2-Furylcarbinol ; 5-Hydroxymethylfuran ; 2-Hydroxymethylfuran ; Furfuranol ; Furfurylcarb ; Furylcarbinol (VAN) ; Methanol, (2-furyl)- ; alpha-Furylcarbinol . Furfuryl alcohol is an organic compound containing a furan substitited with a hydroxymethyl group. It is a clear amber liquid with a faint burning odor and a bitter taste. It is soluble in common organic solvents. Upon treatment with acids, heat and/or catalysts,   furfuryl alcohol can be made to polymerize into a resin, poly .

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