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Cas Database

Name	GLYCOLIC ALDEHYDE	EINECS	N/A
CAS No.	141-46-8	Density	1.065g/cm³
PSA	37.30000	LogP	-0.82240
Solubility	N/A	Melting Point	97°C
Formula	C2H4 O2	Boiling Point	131.3°Cat760mmHg
Molecular Weight	60.0526	Flash Point	42°C
Transport Information	N/A	Appearance	N/A
Safety	A poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.	Risk Codes	N/A
Molecular Structure		Hazard Symbols	Moderately toxic by ingestion.
Synonyms	Glycolaldehyde(8CI); 2-Hydroxyacetaldehyde; 2-Hydroxyethanal; 2-Oxoethanol; Diose; Glycolicaldehyde; Hydroxyacetaldehyde; Hydroxyethanal; Methylolformaldehyde;Monomethylolformaldehyde; NSC 67935	Article Data	333

GLYCOLIC ALDEHYDE Synthetic route

: 50-00-0
formaldehyd

: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
With N,N-dibutylacetamide; trimethylbenzoic acid; acetylacetonatodicarbonylrhodium(l); 2-phospha-2-(2-N,N-dimethylcarbamoylethyl)-1,3,5,7-tetramethyl-6,9,10-trioxatricyclo[3.3.1.1(3,7)]decane In water at 90℃; for 5h; Product distribution / selectivity;	90%
With sodium hydroxide; Wang resin-pentylstyrene[5-Ph(4Me)]N-Me-imidazole(1+)*Cl(1-) In tetrahydrofuran for 0.166667h; Heating;	77%
With 1-methyl-pyrrolidin-2-one; trimethylbenzoic acid; acetylacetonatodicarbonylrhodium(l); 6-phospha-2,4,8-trioxa-1,3,5,7-tetramethyladamantyl(n-C20H41) at 110℃; for 2h; Product distribution / selectivity;	76%

: 50-00-0
formaldehyd

: 16842-03-8, 64519-62-6
hydridocobalt tetracarbonyl

A: 67-56-1
methanol

B: 15226-74-1, 61091-28-9, 61117-58-6
dicobalt octacarbonyl

C: 107-31-3
Methyl formate

D: 107-21-1
ethylene glycol

E: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
In dichloromethane reaction of gaseous formaldehyde with excess of HCo(CO)4 in CH2Cl2 (0°C, 1 h), color of soln. turning brown; IR, 1H NMR;	A 80% B n/a C 0% D 0% E 0%

...Expand

: 452-51-7, 13046-70-3, 29780-54-9, 36792-87-7, 36792-88-8, 113890-35-0, 113890-38-3
D-2-deoxyribose

A: 110-00-9
furan

B: 75-07-0
acetaldehyde

C: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
at 358℃; for 0.000833333h; Product distribution; Curie-point pyrolysis;	A 15.3% B 74% C 2%

: 131543-46-9
Glyoxal

: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
	73.6%
	70%

: 532-20-7, 613-83-2, 7261-25-8, 7687-39-0, 13221-22-2, 14795-83-6, 15761-67-8, 20074-49-1, 25545-03-3, 25545-04-4, 32445-75-3, 34436-17-4, 36441-93-7, 36468-53-8, 37110-85-3, 37388-49-1, 38029-69-5, 40461-77-6, 40461-89-0, 41546-19-4, 41546-20-7, 41546-21-8, 41546-26-3, 41546-29-6, 41546-30-9, 41546-31-0, 126872-16-0, 131064-98-7
D-Ribose

A: 98-01-1
furfural

B: 141-46-8
Glycolaldehyde

C: 116-09-6
hydroxy-2-propanone

Conditions

Conditions	Yield
at 358℃; for 0.000833333h; Product distribution; Curie-point pyrolysis;	A 71.7% B 12.4% C 5.4%

: 74-85-1
ethene

A: 131543-46-9
Glyoxal

B: 107-21-1
ethylene glycol

C: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
With periodate; permanganate(VII) ion In water	A 10% B 19% C 71%

: 489-91-8, 528-16-5, 552-12-5, 577-46-8, 643-33-4, 2240-07-5, 6294-16-2, 10133-02-5, 18402-78-3, 18968-14-4, 21179-08-8, 23018-83-9, 33599-45-0, 33599-46-1, 46171-67-9, 46171-69-1, 46172-26-3, 70021-34-0, 71031-08-8, 104195-06-4, 106499-29-0, 124817-72-7
D-galacturonic acid

A: 110-00-9
furan

B: 98-01-1
furfural

C: 141-46-8
Glycolaldehyde

D: 67-64-1
acetone

Conditions

Conditions	Yield
at 358℃; for 0.000833333h; Product distribution; Curie-point pyrolysis;	A 3.2% B 69.8% C 3.1% D 8.6%

: 50-99-7
D-glucose

: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
In water at 500℃; for 5.64h; Catalytic behavior; Reagent/catalyst;	69.3%
With water; magnesium carbonate
With water; calcium carbonate

: 28697-53-2
D-arabinopyranose

A: 98-01-1
furfural

B: 141-46-8
Glycolaldehyde

C: 116-09-6
hydroxy-2-propanone

Conditions

Conditions	Yield
at 358℃; for 0.000833333h; Product distribution; Curie-point pyrolysis;	A 66.6% B 24.3% C 3.9%

: 6347-01-9
fructopyranose

A: 98-01-1
furfural

B: 141-46-8
Glycolaldehyde

C: 116-09-6
hydroxy-2-propanone

Conditions

Conditions	Yield
at 358℃; for 0.000833333h; Product distribution; Curie-point pyrolysis;	A 65% B 17.4% C 6.4%

GLYCOLIC ALDEHYDE Chemical Properties

Glycolic aldehyde(141-46-8)'s molecular formula is C₂H₄O₂ and its formula weight is 60.0520 .
The molecular structure of glycolic aldehyde(141-46-8):

This glycolic aldehyde(141-46-8)'s structure is also available as a 2d Mol file or as a computed 3d Mol file.

GLYCOLIC ALDEHYDE Toxicity Data With Reference

1.	mic-sat 12500 nmol/plate	JCROD7 Journal of Cancer Research and Clinical Oncology. 111 (1986),149.
2.	mrc-orl-uns-dmg 125 mmol/L	CRNGDP Carcinogenesis. 17 (1996),1083.
3.	dnd-hmn-lym 5 mmol/L	MUREAV Mutation Research. 304 (1994),229.
4.	orl-rat LDLo:3 g/kg	AJCPAI American Journal of Clinical Pathology. 45 (1966),46.
5.	ipr-rat LD50:280 mg/kg	TXAPA9 Toxicology and Applied Pharmacology. 71 (1983),84.

GLYCOLIC ALDEHYDE Safety Profile

A poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.

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