- Gibberellic Acid
- Gibberellic acid(GA3)
- 77065-87-3Inosine 5'-(trihydrogendiphosphate), P'-anhydride with phosphorothioic acid
- 7706-67-4Dimecrotic acid
- 770671-04-01-(3-(4-methylpiperazin-1-yl)phenyl)guanidine
- 770-69-4Tricyclo[3.3.1.13,7]decane,1-ethyl-
- 770700-55-51H-1,4-Diazepine,1-(3-fluoropropyl)hexahydro-
- 770-71-81-Adamantanemethanol
- 770721-33-06-Feruloylcatalpol
- 77074-14-7SUCCINIMIDYL PROPIONATE, N-, [PROPIONATE-2,3-3H]
- 770742-93-3D-Cysteine,S-2-propen-1-yl-
- 77074-61-4Acetonitrile,2-[[2,6-dimethyl-4-[[(methylamino)carbonyl]oxy]phenyl]amino]-
Hot Products
- 3710-84-7Ethanamine,N-ethyl-N-hydroxy-
- 521-18-6Androstan-3-one,17-hydroxy-, (5a,17b)-
- 127-19-5N,N-Dimethylacetamide
- 87-66-1Pyrogallol
- 41340-25-4Etodolac
- 12650-69-0Mupirocin
- 33089-61-1Amitraz
- 87413-09-0Dess-Martin periodinane
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
Gibberellic Acid |
EINECS | 201-001-0 |
| CAS No. | 77-06-5 | Density | 1.49 g/cm3 |
| PSA | 104.06000 | LogP | 1.02710 |
| Solubility | 5 g/L (20 °C) in water | Melting Point |
227 °C |
| Formula | C19H22O6 | Boiling Point | 628.6 °C at 760 mmHg |
| Molecular Weight | 346.38 | Flash Point | 231.4 °C |
| Transport Information | N/A | Appearance | white powder |
| Safety | 26-36 | Risk Codes | 36 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Gibb-3-ene-1,10-dicarboxylic acid, 2,4a,7-trihydroxy-1-methyl-8-methylene-, 1,4a-lactone;4a,1-(epoxymethano)-7,9a-methanobenz[a]azulene-10-carboxylic acid, 1,2,4b,5,6,7,8,9,10,10a-decahydro-2,7-dihydroxy-1-methyl-8-methylene-13-oxo-;Activol GA;Monopotassium 2,4a,7-trihydroxy-1-methyl-8-methylenegibb-3-ene-1,10-dicarboxylate 1,4a-lactone, (1alpha,2beta,4aalpha,4bbeta,10beta)-;Gibberellic acid (GA3);2beta,4aalpha,7-Trihydroxy-1beta-methyl-8-methylene-4aalpha,4bbeta-gibb-3-ene-1alpha,10beta-dicarboxylic acid 1,4a-lactone;2,4a, 7-Trihydroxy-1-methyl-8-methylenegibb-3-ene-1,10-carboxylic acid 1-4-lactone;Pgr-iv;Monopotassium gibberellate;Gibrescol;GA3;Pro-Gibb Plus;Gibefol;Gib-Tabs;EPA Pesticide Chemical Code 043802;(1R,2R,5S,8S,9S,10R,11S,12S)-5,12-dihydroxy-11-methyl-6-methylidene-16-oxo-15-oxapentacyclo[9.3.2.1(5,8).0(1,10).0(2,8)]heptadec-13-ene-9-carboxylic acid;Grocel;Acide gibberellique [ISO-French];Gibb-3-ene-1,10-dicarboxylic acid, 2,4a, 7-trihydroxy-1-methyl-8-methylene-, 1,4a-lactone, (1.alpha., 2.beta.,4a.alpha.,4b.beta.,10.beta.)-;Ralex;Regulex;Gibberellic acid ( GA3 );Giberillic acid;Gibberellic-acid;Gibberellic acid (GA3 );Activol;Gibberellins;EPA Pesticide Chemical Code 043801;2beta,4alpha,7-Trihydroxy-1-methyl-8-methylene-4aalpha,4bbeta-gibb-3-ene-1alpha,10beta-dicarboxylic acid 1,4a-lactone;Brellin;Gibberellic acid GA3;Ryzup;Gibb-3-ene-1,10-dicarboxylic acid, 2,4a,7-trihydroxy-1-methyl-8-methylene-, 1,4a-lactone, monopotassium salt, (1alpha,2beta,4aalpha,4bbeta,10beta)-;NCI-C55823;2,7-dihydroxy-1-methyl-8-methylene-13-oxo-1,2,4b,5,6,7,8,9,10,10a-decahydro-4a,1-(epoxymethano)-7,9a-methanobenzo[a]azulene-10-carboxylic acid;Berelex;Gibberellin A3;2beta,4alpha,7-Trihydroxy-1-methylene-4aalpha,4bbeta-gibb-3-ene-1alpha,10beta-dicarboxylic acid 1,4a-lactone;Gib-Sol;Gibberellin X;Gibberellin;Gibberellinsaeure;Pro-Gibb;Release LC;Maxon (plant growth regulator);Gibberellins A4A7;Cekugib;Gibrofit; |
Article Data | 10 |
Gibberellic Acid Synthetic route
- 19123-33-2
2β,4a,7-trihydroxy-1-methyl-8-methylene-gibb-3-ene-1α,10β-dicarboxylic acid 10,10'-anhydride 1->4a;1'->4'a-dilactone
A
- 54878-53-4
GA3-7-alkohol
B
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate; acetic acid In tetrahydrofuran for 0.5h; Yield given; | A 72% B n/a |
| With sodium tetrahydroborate; acetic acid In tetrahydrofuran for 0.5h; other conditions; Yields of byproduct given; | A 72% B n/a |
- 5087-25-2, 58917-17-2
gibberellin A3-ketone
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
| Conditions | Yield |
|---|---|
| With potassium dihydrogenphosphate; potassium tri-sec-butyl-borohydride |
- 19147-54-7, 65563-70-4
Diacetyl-gibberellinsaeure
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
| Conditions | Yield |
|---|---|
| With sodium methylate In N,N-dimethyl-formamide at 23℃; for 4h; |
- 561-56-8
gibberellin A5
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
| Conditions | Yield |
|---|---|
| With air; alpha-ketoglute dipotassium; potassium ascorbate; iron(II) sulfate In various solvent(s) at 30℃; for 2h; enzyme preparation from anthers of Oryza sativa L., pH 8.0; Yield given; |
- 53060-60-9
ent-7α-hydroxykaurene
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
| Conditions | Yield |
|---|---|
| With Giberella fujikuroi at 25℃; for 24h; incubation; |
- 54878-55-6
0(3),0(13)-Diacetyl-gibberellin-A3-7-aldehyd
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: PDC / dimethylformamide / 3.5 h / 23 °C 2: NaOCH3 / dimethylformamide / 4 h / 23 °C View Scheme |
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
A
- 427-79-2, 13613-87-1, 19123-39-8, 26688-43-7, 28862-60-4, 38045-67-9
allogibberic acid
B
- 13613-87-1
(4bR,7S,9aS,10R)-7-hydroxy-1-methyl-8-methylene-4b,6,7,8,9,10-hexahydro-5H-7,9a-methanobenzo[a]azulene-10-carboxylic acid
| Conditions | Yield |
|---|---|
| With sodium carbonate at 240℃; Product distribution; 1-5 min; | A n/a B 100% |
| With sodium carbonate at 240℃; 1-5 min; | A n/a B 100% |
| With hydrazine |
- 108-24-7
acetic anhydride
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
- 19147-54-7, 65563-70-4
Diacetyl-gibberellinsaeure
| Conditions | Yield |
|---|---|
| With pyridine; dmap for 12h; Cooling with ice; Inert atmosphere; | 99% |
| With pyridine Ambient temperature; | 2.0 g |
- 821-41-0
5-Hexen-1-ol
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
| Conditions | Yield |
|---|---|
| With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 16h; Inert atmosphere; | 99% |
- 77-06-5
(3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid
- 74-88-4
methyl iodide
- 510-50-9
gibberellic acid methyl ester
| Conditions | Yield |
|---|---|
| With potassium carbonate In acetone | 98% |
| With potassium carbonate In acetone at 20℃; Inert atmosphere; | 95.4% |
| With potassium carbonate In acetone at 18℃; for 20h; | 94% |
| With potassium carbonate In acetone | 92% |
| With cesium fluoride In N,N-dimethyl-formamide for 24h; Ambient temperature; | 407 mg |
Gibberellic Acid Chemical Properties
Empirical Formula: C19H22O6
Molecular Weight: 346.3744
EINECS: 201-001-0
Structure of Gibberellic Acid (CAS NO.77-06-5):
Index of Refraction: 1.661
Molar Refractivity: 85.786 cm3
Molar Volume: 231.972 cm3
Polarizability: 34.008 10-24cm3
Surface Tension: 71.863 dyne/cm
Density: 1.493 g/cm3
Flash Point: 231.438 °C
Enthalpy of Vaporization: 106.599 kJ/mol
Melting Point: 227 °C
Boiling Point: 628.595 °C at 760 mmHg
Vapour Pressure: 0 mmHg at 25°C
Storage temp: 0-6°C
Water Solubility: 5 g/L (20 º C)
Stability: Stable. Combustible. Incompatible with acids, strong oxidizing agents.
Product Categories: FINE Chemical & INTERMEDIATES; Plant Oils, Toxins, Phenolic Acids & Derivatives; Biochemistry; Plant Growth Regulators; Plant Growth Trgulators (Others); Antibiotic Explorer
Synonyms of Gibberellic Acid (CAS NO.77-06-5): (1alpha,2beta,4aalpha,4bbeta,10beta)-2,4a,7-Trihydroxy-1-methyl-8-methylenegibb-3-ene-1,10-dicarboxylic acid 1,4a-lactone ; (3S,3aR,4S,4aS,7S,9aR,9bR,12S)-7,12-Dihydroxy-3-methyl-6-
methylene-2-oxoperhydro-4a,7-methano-9b,3-propenoazuleno(1,2-b)furan-4-carboxylic acid ; Activol ; Berelex ; Brellin ; CCRIS 4820 ; Caswell No. 467 ; Cekugib ; Gibberellin ; Gibberellin A3 ; Gibefol ; Gibrescol ; Gibreskol ; Grocel ; Pro-Gibb Plus ; Regulex ; Ryzup
Gibberellic Acid Uses
Gibberellic acid has the main following uses:
1.Gibberellic acid is a very potent hormone whose natural occurrence in plants controls their development. Since Gibberellic acid regulates growth, applications of very low concentrations can have a profound effect while too much will have the opposite effect. It is usually used in concentrations between 0.01-10 mg/L.
2.Gibberellic acid is a simple gibberellin, promoting growth and elongation of cells.
3.Gibberellic acid is sometimes used in laboratory and greenhouse settings to trigger germination in seeds that would otherwise remain dormant. It is also widely used in the grape-growing industry as a hormone to induce the production of larger bundles and bigger grapes, especially Thompson seedless grapes, and in the Okanagan and Creston Valley it is used in the cherry industry as a growth regulator.
Gibberellic Acid Toxicity Data With Reference
| 1. | dnd-sal:spr 1 mmol/L | PYTCAS Phytochemistry. An International Journal of Plant Biochemistry. 11 (1972),3135. | ||
| 2. | dnd-mam:lym 1 mmol/L | PYTCAS Phytochemistry. An International Journal of Plant Biochemistry. 11 (1972),3135. | ||
| 3. | orl-mus TDLo:142 g/kg/78W-I:ETA | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB223-159 . | ||
| 4. | orl-rat LD50:6300 mg/kg | 85ARAE Agricultural Chemicals, Books I, II, III, and IV. 3 (1976/77),43. |
Gibberellic Acid Consensus Reports
EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.
Gibberellic Acid Safety Profile
Hazard Codes: 
Xi
Risk Statements: 36
R36:Irritating to eyes.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany: 3
RTECS: LY8990000
F: 10
HS Code: 29322980
Hazardous Substances Data 77-06-5(Hazardous Substances Data)
Mildly toxic by ingestion of gibberellic acid . It is showed to be questionable carcinogen by experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes.
What can I do for you?
Get Best Price
