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Name	Iridium trichloride	EINECS	233-044-6
CAS No.	10025-83-9	Density	5,3 g/cm3
PSA	0.00000	LogP	-8.98800
Solubility	insoluble in water	Melting Point	763 °C(lit.)
Formula	IrCl₃	Boiling Point	N/A
Molecular Weight	298.579	Flash Point	N/A
Transport Information	N/A	Appearance	brown powder
Safety	26-36	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Iridium (III) chloride;Iridium chloride (IrCl3);	Article Data	41

Iridium trichloride Synthetic route

: iridium

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
With Cl2 In neat (no solvent) in a flow of Cl2 (free from O2, 1 atm) at 500-620°C; at 600-620°C instantaneous reation; at 445 °C only incomplete reaction even after several hours;; sintering at 650°C;	100%
With chlorine
With chlorine Irradiation (UV/VIS); reacting with chlorine at 600-620°C by irradn. of sunshine or of magnesium light;

: iridium

A: iridium(III) chloride

B: 10025-83-9
iridium (III) chloride

C: iridium(I)-chloride

Conditions

Conditions	Yield
With chlorine above 600°C, by decompn.;
With Cl2 above 600°C, by decompn.;

: 80937-33-3
oxygen

: iridium

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
at red heat; product is a mixt. of Ir and IrCl3;
at red heat; product is a mixt. of Ir and IrCl3;

: BaO*CO2=BaCO3

: 3H(1+)*{IrCl4(C2O4)}(3-)*99H2O=H3{IrCl4(C2O4)}*99H2O

A: 10025-83-9
iridium (III) chloride

B: 516-02-9
barium oxalate

Conditions

Conditions	Yield
In water filtering;evapn.;

: iridium(III) trichloride hydrate

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
With Cl2 In neat (no solvent) byproducts: H2O; heating IrCl3*H2O in a flow of chlorine at 450-600 °C, reaction starts even at 310 °C;;
at 310°C;

: 3K(1+)*{IrCl6}(3-)*3H2O=K3{IrCl6}*3H2O

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;

: 3Na(1+)*{IrCl6}(3-)*12H2O=Na3{IrCl6}*12H2O

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
With hydrogenchloride In neat (no solvent) at 440°C;
With HCl In neat (no solvent) at 440°C;

: iridium(IV) oxide dihydrate

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
With chlorine by heating;
With Cl2 by heating;

: potassium hexachloroiridate(III)

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
With hydrogenchloride at 440 °C;
With HCl at 440 °C;

: silver iridium(III) chloride

: 10025-83-9
iridium (III) chloride

Conditions

Conditions	Yield
With hydrogenchloride byproducts: AgCl contg. Ir;
With HCl byproducts: AgCl contg. Ir;

Iridium trichloride Specification

The Iridium chloride is an organic compound with the formula IrCl₃. The IUPAC name of this chemical is iridium(3+) trichloride. With the CAS registry number 10025-83-9, it is also named as Iridium trichloride. The product's categories are Inorganics; Iridium Salts; Metal and Ceramic Science; Salts; Crystal Grade Inorganics; IridiumMetal and Ceramic Science.

Physical properties about Iridium chloride are: (1)Enthalpy of Vaporization: 16.15 kJ/mol ; (2)Vapour Pressure: 33900 mmHg at 25°C.

Preparation: this chemical can be prepared by Iridium powder and chlorine mixed with a small amount of carbon monoxide. The reaction time is 15 min with reaction temperature of 600 °C.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Ir](Cl)Cl
(2)InChI: InChI=1/3ClH.Ir/h3*1H;/q;;;+3/p-3
(3)InChIKey: DANYXEHCMQHDNX-DFZHHIFOAH
(4)Std. InChI: InChI=1S/3ClH.Ir/h3*1H;/q;;;+3/p-3
(5)Std. InChIKey: DANYXEHCMQHDNX-UHFFFAOYSA-K

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