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Isopropyl glycidyl ether
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Name

Isopropyl glycidyl ether

 EINECS 223-672-9
CAS No. 4016-14-2 Density 0.955 g/cm3
PSA 21.76000 LogP 0.81020
Solubility

Stability

    Stable. Flammable. Incompatible with strong oxidizing agents.

Toxicology

    Skin irritant. May act as a sensitizer.

    Toxicity data
    (The meaning of any tox

Melting Point N/A
Formula C6H12 O2 Boiling Point 131ºC at 760 mmHg
Molecular Weight 116.16 Flash Point 33.3 ºC
Transport Information N/A Appearance colourless liquid
Safety Suspected carcinogen. Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin and eye irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes. See also GLYCOL ETHERS.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Isopropyl Glycidyl Ether S77.

Risk Codes 10-19-36/37/38-43
Molecular Structure Molecular Structure of 4016-14-2 (GLYCIDYL ISOPROPYL ETHER) Hazard Symbols Flammable liquid with flash p 92F (33.33C). TLV: TWA 50 ppm; STEL 75 ppm. Skin, eye, and respiratory irritant.
Synonyms

Oxirane,[(1-methylethoxy)methyl]- (9CI); Propane, 1,2-epoxy-3-isopropoxy-(6CI,7CI,8CI); (Isopropoxymethyl)oxirane; (Isopropyloxymethyl)oxirane; (?à)-Glycidyl isopropyl ether;1,2-Epoxy-3-isopropoxypropane; 2,3-Epoxypropyl isopropyl ether;2-(Isopropoxymethyl)oxirane; 3-Isopropoxy-1,2-epoxypropane;3-Isopropyloxypropylene oxide; Glycidyl isopropyl ether; Isopropyl glycidylether; NSC 4127; NSC 46562; [(1-Methylethoxy)methyl]oxirane

Article Data 11

Isopropyl glycidyl ether Chemical Properties

IUPAC Name: 2-(Isopropoxymethyl)oxirane
CAS: 4016-14-2
EINECS: 223-672-9
Product Categories: Oxiranes ; Simple 3-Membered Ring Compounds .
Following is the Molecular Structure of Isopropyl glycidyl ether (4016-14-2):

SMILES: O(C(C)C)CC1OC1
InChI: InChI=1/C6H12O2/c1-5(2)7-3-6-4-8-6/h5-6H,3-4H2,1-2H3
InChIKey: NWLUZGJDEZBBRH-UHFFFAOYAX
Std.InChI: InChI=1S/C6H12O2/c1-5(2)7-3-6-4-8-6/h5-6H,3-4H2,1-2H3
Std.InChIKey: NWLUZGJDEZBBRH-UHFFFAOYSA-N
Molecular Formula: C6H12O2
Molecular Weight: 116.16
Boiling Point: 131℃ at 760mmHg
Flash Point: 33.3℃
Molar Volume: 121.6 cm3
Density: 0.955g/cm3
Index of Refraction: 1.425
Molar Refractivity: 31.12cm3
Surface Tension: 30.3dyne/cm
Polarizability: 12.33 10-24cm3
Enthalpy of Vaporization: 35.34kJ/mol
Vapour Pressure: 11.6mmHg at 25℃

Isopropyl glycidyl ether Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 1500ppm/4H (1500ppm) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LIVER: OTHER CHANGES		 AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
mouse LD50 oral 1300mg/kg (1300mg/kg) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA		 AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rabbit LD50 skin 9650mg/kg (9650mg/kg) LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rat LC50 inhalation 1100ppm/8H (1100ppm) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LIVER: OTHER CHANGES		 AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rat LD50 oral 4200mg/kg (4200mg/kg) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA		 AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.

Isopropyl glycidyl ether Consensus Reports

 Glycol ether compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Isopropyl glycidyl ether Safety Profile

Hazard Codes:  Xi Irritant.
Risk Statements: 10-19-36/37/38-43
R10:  Flammable.
R19: May form explosive peroxides.
R36/37/38: Irritating to eyes, respiratory system and skin.
R43: May cause sensitization by skin contact.
Safety Statements: 16-26-36/37
S16: Keep away from sources of ignition-No smoking.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 3271 3/PG 3
WGK: Germany 2
RTECS: TZ3500000
Suspected carcinogen. Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin and eye irritant.

Isopropyl glycidyl ether Standards and Recommendations

OSHA PEL: TWA 50 ppm; STEL 75 ppm
ACGIH TLV: TWA 50 ppm; STEL 75 ppm
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Glycidyl Ethers) CL 240 mg/m3/15M

Isopropyl glycidyl ether Analytical Methods

For occupational chemical analysis use NIOSH: Isopropyl Glycidyl Ether S77.

Isopropyl glycidyl ether Specification

 Isopropyl glycidyl ether (4016-14-2),which also can be called for ((1-Methylethoxy)methyl)-oxiran ; [(1-Methylethoxy)methyl]-oxiran ; 1,2-Epoxy-3-isopropoxy-propan ; 2-(Isopropoxymethyl)oxirane ; 3-Isopropoxy-1,2-epoxypropane ; 3-Isopropyloxypropylene oxide ; 3-Isopropyloxypropyleneoxide ; Isopropyl epoxypropyl ether .Stable. Isopropyl glycidyl ether (4016-14-2) is flammable and it's incompatible with strong oxidizing agents.It's a colorless liquid and it should be stored at -20℃.When  Isopropyl glycidyl ether (4016-14-2) was heated,it emits acrid smoke and fumes.

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