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Isopropylmagnesium chloride

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Name

Isopropylmagnesium chloride

EINECS 213-947-1
CAS No. 1068-55-9 Density 0.98 g/mL at 20 °C
PSA 0.00000 LogP 2.05350
Solubility It reacts violently with water. Melting Point 155-157 °C
Formula C3H7ClMg Boiling Point 256 °C
Molecular Weight 102.847 Flash Point 72 °F
Transport Information UN 3399 4.3/PG 2 Appearance powder
Safety 26-36/37/39-43-45 Risk Codes 10-11-12-14/15-19-22-34-66-67
Molecular Structure Molecular Structure of 1068-55-9 (ISOPROPYLMAGNESIUM CHLORIDE) Hazard Symbols CorrosiveC, HighlyF+, FlammableF
Synonyms

Isopropylmagnesiumchloride (6CI);Magnesium, chloroisopropyl- (7CI,8CI);2-Propylmagnesiumchloride;Chloroisopropylmagnesium;

Article Data 19

Isopropylmagnesium chloride Synthetic route

75-29-6

isopropyl chloride

1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
With magnesium In tetrahydrofuran-d8 at 80℃; under 5171.62 Torr; Temperature; Concentration; Inert atmosphere; Flow reactor;95%
With magnesium In tetrahydrofuran at 21 - 29℃; for 0.5h; Inert atmosphere; Flow reactor;94.5%
With magnesium In tetrahydrofuran
75-29-6

isopropyl chloride

A

1068-55-9

isopropylmagnesium chloride

B

3536-97-8

diisopropylmagnesium

Conditions
ConditionsYield
With diethyl ether; magnesium In toluene Ambient temperature; solvatation of Grignard reagent by diethyl ether;
75-29-6

isopropyl chloride

7439-95-4

magnesium

1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran at 40℃;
1194059-56-7

C11H19NO4

1194059-55-6

C17H33NO4Si

90965-06-3

dimethyl 1-(1-diazo-2-oxopropyl)phosphonate

A

1194059-57-8

C18H33NO3Si

B

1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
Stage #1: dimethyl 1-(1-diazo-2-oxopropyl)phosphonate With 4-toluenesulfonyl azide; potassium carbonate In acetonitrile at 0 - 20℃; for 2h; Bestmann alkynylation; Inert atmosphere; Cooling with ice bath;
Stage #2: C11H19NO4; C17H33NO4Si In methanol; acetonitrile at 20℃; Inert atmosphere;
75-29-6

isopropyl chloride

magnesium

magnesium

1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
With diethyl ether
930-68-7

cyclohexenone

1068-55-9

isopropylmagnesium chloride

23396-36-3

3-isopropylcyclohexanone

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride With copper(l) chloride In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere;
Stage #2: cyclohexenone With chloro-trimethyl-silane In tetrahydrofuran at -78℃; for 20h; Inert atmosphere;
100%
With zinc(II) chloride; (2S,2'S)-2-hydroxymethyl-1-<(1-methylpyrrolidine-2-yl)methyl>pyrrolidine In tetrahydrofuran at -90℃; for 0.25h;97%
Grignard Reaction;78%
1068-55-9

isopropylmagnesium chloride

78129-68-7

2,2-dimethylpropylidynephosphine

(Z)-1-tert-butyl-2-isopropyl-2-phosphavinylmagnesium chloride

Conditions
ConditionsYield
In diethyl ether at -78 - 20℃; for 14.5h;100%
1068-55-9

isopropylmagnesium chloride

452307-58-3

7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-carbonitrile

452307-59-4

1-[7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-yl]-2-methylpropan-1-one

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride; 7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-carbonitrile With copper(I) bromide In tetrahydrofuran
Stage #2: With sulfuric acid In tetrahydrofuran
100%
67242-74-4

(E)-1-chloro-2-nonene

1068-55-9

isopropylmagnesium chloride

3-isopropyl-non-1-ene

Conditions
ConditionsYield
CUCl-N-heterocyclic carbene In diethyl ether at 0℃;100%
1068-55-9

isopropylmagnesium chloride

163976-62-3

[(Z)-4-[(tert-butyldimethylsilyl)oxy]-2-buten-1-yl] ethyl carbonate

tert-butyl-(2-isopropyl-but-3-enyloxy)-dimethyl-silane

Conditions
ConditionsYield
CuCl - N-heterocyclic carbene In diethyl ether at 0℃;100%

Isopropylmagnesium chloride Specification

The Magnesium,chloro(1-methylethyl)-, with the CAS registry number 1068-55-9, has the IUPAC name of magnesium propane chloride. Its product categories are including Classes of Metal Compounds; Grignard Reagents; Grignard Reagents & Alkyl Metals; Mg (Magnesium) Compounds; Synthetic Organic Chemistry; Typical Metal Compounds; AlkylChemical Synthesis; Grignard Reagents; Organic Bases; Organometallic Reagents; Synthetic Reagents.

The physical properties of this chemical are as follows: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 1; (4)Polar Surface Area: 0; (5)Exact Mass: 102.00867; (6)MonoIsotopic Mass: 102.00867; (7)Heavy Atom Count: 5; (8)Complexity: 6.9; (9)Covalently-Bonded Unit Count: 3.

Use of this chemical: Magnesium,chloro(1-methylethyl)- could react with isobutyryl chloride to produce 2,4-dimethyl-pentan-3-one. This reaction could happen in the presence of the reagent of diethyl ether.

When you are dealing with this chemical, you should be very cautious. For one thing, it is extremely flammable which may have an extremely low flash point and boiling point, and gases that catch fire in contact with air. For another thing, it is corrosive which may destroy living tissue on contact. Besides, it could react violently with water, liberating extremely flammable gases and then may form explosive peroxides. In addition, the repeated exposure may cause skin dryness or cracking and then the vapours may cause drowsiness and dizziness.

Therefore, you should take the following instructions to deal with different cases. The first important thing is to wear suitable protective clothing, gloves and eye/face protection. And if in case of contact with eyes, rinse immediately with plenty of water and seek medical advice; In case of fire use ... (there follows the type of fire-fighting equipment to be used.); In case of accident or if you feel unwell, seek medical advice immediately (show the

In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: C[CH-]C.[Mg+2].[Cl-]
(2)InChI: InChI=1S/C3H7.ClH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q-1;;+2/p-1
(3)InChIKey: IUYHWZFSGMZEOG-UHFFFAOYSA-M 

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